crosslinked poly(acrylic acid)s were prepared using two types of crosslinker by precipitation polymerization method in a binary organic solvent. n,n’-methylenebisacrylamide (mba) and polyethylene glycol dimethacrylate (pegdma-330) were used as low-molecular weight and long-chain crosslinkers, respectively. the effect of various types of crosslinkers on polymer characteristics (i.e., gel content...

Convenient methods for the rapid, parallel synthesis of diversely functionalized nanoparticles will enable discovery of novel formulations for drug delivery, biological imaging, and supported catalysis. In this report, we demonstrate parallel synthesis of brush-arm star polymer (BASP) nanoparticles by the "brush-first" method. In this method, a norbornene-terminated poly(ethylene glycol) (PEG) ...

Sulfur or peroxide crosslinking is the most common and conventional method to develop elastomeric materials. A new approach crosslink epoxidized natural rubber (ENR) by aminopropyl terminated polydimethylsiloxane (AT-PDMS) described, intending a kind of hybrid organic–inorganic elastomers. The curing reaction accelerated using hydroquinone as catalyst. formation structure evident from appearanc...

long-chain diacrylate crosslinkers based on linear α,ω-diols were synthesized and characterized using ftir and 1h nmr spectroscopy. the highest reaction yield (99.5%) was due to polyethylene glycol diacrylate 1000 (pegda-1000). then, kaolin-containing poly(potassium acrylate-acrylic acid) superabsorbent composites and kaolin-free counterparts were synthesized using pegda-1000.the effect of the ...

The nanoparticles of templated crosslinked chitosan, was prepared through using ECH as a crosslinker. The nanoparticles exhibited significantly higher adsorption capacities from the congo red dye than other adsorbent formed without a crosslinker. The adsorption of the dyes on the nanoparticles was affected by the initial pH, dye concentration, and temperature. The results were in accordance wit...

A class of new biodegradable hydrogels based on poly(ethylene glycol) methacrylate-graft-poly(glutamic acid) and poly(ethylene glycol) dimethacrylate was synthesized by photoinduced polymerization. Because all the polymeric constituents were highly hydrophilic, crosslinking could be performed in aqueous solutions. This type of crosslinked hydrogel was prepared by modifying a select number of ac...

Classical Molecular Dynamics (MD) simulations provide insight into the properties of many soft-matter systems. In some situations, it is interesting to model the creation of chemical bonds, a process that is not part of the MD framework. In this context, we propose a parallel algorithm for step- and chain-growth polymerization that is based on a generic reaction scheme, works at a given intrins...