The adhesion of supported polymer thin fi lms is predominantly infl uenced by the substrate-fi lm interfacial properties. Utilizing steered molecular dynamics simulations, here we uncover that the cohesive noncovalent forces between polymer chains in the fi lm also have a signifi cant effect on the adhesive properties of supported fi lm. We demonstrate that weaker interchain interactions, all e...

For membrane-associated enzymes, which access substrate from either a monolayer or bilayer of the aggregate substrate, the partitioning from the aqueous phase to this phospholipid interface is critical for catalysis. Despite a large and expanding body of knowledge regarding interfacial enzymes, the biophysical steps involved in interfacial recognition and adsorption remain relatively poorly und...

Equations are derived to approximately describe the propagation of small amplitude surface and interfacial waves across small irregularities in depth in a two-layer fluid. When the irregularities are sinusoidal, Bragg interaction effects between an incident surface wave and the bottom corrugations can lead to a large-amplitude reflected interfacial wave or a large-amplitude transmitted interfac...

In flip-chip package, the mismatch of thermal expansion coefficients between the silicon die and packaging substrate induces concentrated stress field around the edges and corners of silicon die during assembly, testing and services. The concentrated stresses result in delamination on many interfaces on several levels of structures, in various length scales from tens of nanometers to hundreds o...

This review is concerned primarily with the correlation between the interfacial interactions and the constitutive properties of low-energy organic surfaces. It starts with a discussion on the estimation of the surface free energy of organic solids from contact angles, followed by a review of the surface energetics and adhesion. The experimental measurements of surface free energy, in most cases...

Internal mesostructures of silica nanofibers were dramatically changed through controlled interfacial interactions of confined lyotropic block copolymer systems in nanocylinders, which were further used as structure-directing templates for the fabrication of porous gold nanofibers with unprecedented nanoarchitectures.

To improve the interfacial bonding of sisal fiber-reinforced polylactide biocomposites, polylactide (PLA) and sisal fibers (SF) were melt-blended to fabricate bio-based composites via in situ reactive interfacial compatibilization with addition of a commercial grade epoxy-functionalized oligomer Joncryl ADR@-4368 (ADR). The FTIR (Fourier Transform infrared spectroscopy) analysis and SEM (scanni...

Vibrational sum-frequency spectroscopy (VSFS) is employed here to study the bonding and structure of water molecules at the mixed halocarbon–water interface. Mixtures of non-polar CCl4 with more polar solvents CHCl3, dichloromethane (DCM), and 1,2-dichloroethane (DCE) are used to vary the polarity of the organic phase. The OH stretching modes of interfacial water molecules are used to character...

To improve the interfacial bonding of sisal fiber reinforced polylactide biocomposites, polylactide (PLA) and sisal fibers (SF) were melt-blended to fabricate bio-based composites via in situ reactive interfacial compatibilization with the addition of an epoxy-functionalized oligomer (ADR). The FTIR analysis and SEM characterization demonstrated that PLA molecular chain was bonded to the fiber ...

In this work, a numerical procedure based on the continuum model is developed and applied to the solvation energy for ground state and the spectral shift against the position and the orientation of the interfacial molecule. The interface is described as a sharp boundary separating two bulk media. The polarizable continuum model (PCM) allows us to account for both electrostatic and nonelectrosta...