Using the evaporating method, the solubility of potassium Nitrate was determined in various mixtures containing Water and Ethanol at 25°C. The results show that the solubility of KNo3 decreases with increasing the mass percent of Ethanol in the mixtures. This trend is along with decreasing the dielectric constant of Water+Ethanol mixtures. Moreover, it can be concluded that the totqal solubilit...

the charge-transfer complexation reaction between iodine and dibenzo- 18-crown- 6 (db18c6) has been studied spectrophotometrically in chloroform solution at different temperatures. the resulting donor-acceptor complex was formulated as (db 18c6…i )i . the spectrophotometric results , as well as the conductivity measurements, indicated that the gradual release of tiiodide ion from its contact io...

A simple extractive spectrophotometric method has been developed for the estimation of miconazole nitratein both pure and pharmaceutical preparation. The method is based on the formation of ion-pair complex of thedrug with acidic dye bromothymol blue (BTB) in acidic condition, followed by its extraction in organic solvent(chloroform). The absorbance was measured against the corresponding blank....

Clonidine hydrochloride is an antihypertensive agent used for migraine prophylaxis, attention deficit hyperactivity disorder, menopausal flushing and Tourette syndrome. The quantity of the active substance in pharmaceutical preparations must be within specific limits, in agreement with the respective label claim. Therefore, the aim of this study was to establish the conditions for two spectroph...

Clonidine hydrochloride is an antihypertensive agent used for migraine prophylaxis, attention deficit hyperactivity disorder, menopausal flushing and Tourette syndrome. The quantity of the active substance in pharmaceutical preparations must be within specific limits, in agreement with the respective label claim. Therefore, the aim of this study was to establish the conditions for two spectroph...

the ion-pair association constant values, related to the reaction +  were determined by means of the nmr spectroscopy. the values of the thermodynamic functions of the ion pairing process were calculated on the basis of the nmr results. in addition, the association entropy was found to be dependent on the temperature. comparing the experimental data and the fuoss theory it is found that  ion-pa...

     A simple and sensitive extractive spectrophotometric method is described for determination of tropicamide. The method is based on the reaction of tropicamide and bromocresol green. The ion-paired colored complex was extracted with chloroform at pH 3. The extracted complex showed maximum absorbance at 423 nm. The complex was stable up to 2 days and obeyed Beer's law over the concentration r...

Using the mixed solvents, (water +ethanol + propanol), the solubility of CdF2 was determined byevaporating method at 25° C. The results showed that the sollbility, s, of CdF2 decreases bydecreasing the dielectric constant of the mixed solvent .Once the solubility of CdF2 was determined,the concentration solubility product, Ksp(c)=4s3, was calculated .Furthermore ,by estimating the meanactivity ...

The charge-transfer complexation reaction between iodine and dibenzo- 18-crown- 6 (DB18C6) has been studied spectrophotometrically in chloroform solution at different temperatures. The resulting donor-acceptor complex was formulated as (DB 18C6…I )I . The spectrophotometric results , as well as the conductivity measurements, indicated that the gradual release of tiiodide ion from its contac...

The formation of charge-transfer complexation between dibenzo-15-crown-5 (DB15C5) and benzo-12-crown-4 (B12C4) (Donor) and iodine is investigated spectrophotometrically in three chlorinated solvents,chloroform, dichloromethane (DCM) and 1,2-dichloroethane (DCE) solution at 25°C. The change in polarityof the solvent also doesn’t affect the stoichiometry of the complexes. Values of formation cons...