to understand the rate of oxidation of sponge irons and its mechanisim, their physical and chemical properties are normally required. in this report attempt has been made to show the results of research on varius pellets and briqutts produced at ahwaz steel complex. in presenting these data, the rate of oxidation of these articles in air between 300 and 600 °c is also quotted and analysed. in a...

due to its ability in chemical oxidation of contaminants, iron nanoparticle is a material of choice to remove lead ions from aquatic solutions. in this study a reduction method in solution phase was applied to synthesize thenanoparticles. afterwards, the size of the synthesized particles were confirmed by scanning electron microscopy. it is worth noting that the nanoparticle dose-variations wer...

nitrate is one of the pollutants of groundwater and the great amount of nitrate in drinking water can bring about some hygienic problems such as methemoglobinema phenomena in children. therefore, this research aims to study the efficiency of photo- fenton in removing nitrate and investigating the variables affecting it in aqueous solutions. this research was carried out in water and wastewater ...

The oxidation of amino acids by Fenton reagent (H2O2 + Fe(II] leads mainly to the formation of NH+4, alpha-ketoacids, CO2, oximes, and aldehydes or carboxylic acids containing one less carbon atom. Oxidation is almost completely dependent on the presence of bicarbonate ion and is stimulated by iron chelators at levels which are substoichiometric with respect to the iron concentration but is inh...

Previous work from our laboratory demonstrated that pyridoxal isonicotinoyl hydrazone (PIH) has in vitro antioxidant activity against iron plus ascorbate-induced 2-deoxyribose degradation due to its ability to chelate iron; the resulting Fe(III)-PIH(2) complex is supposedly unable to catalyze oxyradical formation. A putative step in the antioxidant action of PIH is the inhibition of Fe(III)-med...

The effect of nanostructure on the thermal oxidation of atomized iron has been investigated. Above 500 o C atomized iron is oxidized in the presence of air. However, when iron is compacted with multiwalled carbon nanotubes (MWCNT) this oxidation is shifted by more than 100 o C. Iron is protected by the nanostructure environment A large number of compositions of atomic ratios of iron and MWCNT h...

8-Oxo-7,8-dihydroguanine (8-oxoGua), an important biomarker of DNA damage in oxidatively generated stress, is highly reactive towards further oxidation. Much work has been carried out to investigate the oxidation products of 8-oxoGua by one-electron oxidants, singlet oxygen, and peroxynitrite. This report details for the first time, the iron- and copper-mediated Fenton oxidation of 8-oxoGua and...

Razzell, W. E. (British Columbia Research Council, Vancouver, Canada) and P. C. Trussell. Isolation and properties of an iron-oxidizing Thiobacillus. J. Bacteriol. 85:595-603. 1963. - An organism isolated from acidic copper-leaching waters has been shown to oxidize ferrous ions, sulfur, and metallic sulfides but exhibit peculiar responses to thiosulfate. The name Thiobacillus ferrooxidans has b...

Naturally occurring phytoferritin is a heteropolymer consisting of two different H-type subunits, H-1 and H-2. Prior to this study, however, the function of the two subunits in oxidative deposition of iron in ferritin was unknown. The data show that, upon aerobic addition of 48-200 Fe(2+)/shell to apoferritin, iron oxidation occurs only at the diiron ferroxidase center of recombinant H1 (rH-1)....