Hydrogen and carbon isotope ratios of cellulose nitrate and oxygen isotope ratios of cellulose from C(3), C(4), and Crassulacean acid metabolism (CAM) plants were determined for plants growing within a small area in Val Verde County, Texas. Plants having CAM had distinctly higher deuterium/hydrogen (D/H) ratios than plants having C(3) and C(4) metabolism. When hydrogen isotope ratios are plotte...

Literature data on H /D isotope effects on polarizability are reviewed. An argument based on perturbation theory correlates the isotopic differences with electronic transition moments via vibra­ tional averaging. The contribution of the second moment isotope effect is especially important. The approach is first illustrated with a calculation on H 2/D 2 and then employed to correlate differentia...

Kinetic isotope effects related to the breaking of chemical bonds drive sulfur isotope fractionation during dissimilatory sulfate reduction (DSR), whereas oxygen isotope fractionation duringDSR is dominated by exchange between intercellular sulfur intermediates and water. We use a simplified biochemical model for DSR to explore how a kinetic oxygen isotope effect may be expressed. We then explo...

the upper cretaceous carbonate sequence of ab-deraz formation is well exposed in the kopet- dagh basin. this formation comprises marly limestone and three chalky limestone units. chalky limestone of ab-deraz formation is mainly composed of calcareous dinoflagellate (pithonellid calcispher), cocolithofore and planktonic foraminifera. carbon and oxygen stable isotopes analysis of the third chalky...

Isotope effects are one of the most powerful kinetic tools for determining enzyme mechanisms. There are three methods of measurement. First, one can compare reciprocal plots with labeled and unlabeled substrates. The ratio of the slopes is the isotope effect on V/K, and the ratio of the vertical intercepts is the isotope effect on V(max). This is the only way to determine V(max) isotope effects...

A commercial reagent, known as the isobaric tag for relative and absolute quantification (iTRAQ), makes it possible to analyze multiple samples simultaneously. The ability of iTRAQ to compare relative protein abundances across as many as eight samples is a significant advantage over other stable isotope strategies, such as stable isotope labeling by amino acids in cell culture (SILAC) and isoto...

INTRODUCTION ..................................................................................... 504 ISOTOPE EFFECTS ........................................................................... ’ ....... 504 ISOTOPIC OMPOSITION A D DISCRIMINATION ....................................... 505 Definitions .......................................................................................... 50...