Self diffusion coefficients and binary Maxwell-Stefan diffusion coefficients were determined by equilibrium molecular dynamics simulations with the Green-Kubo method. The study covers five pure fluids: neon, argon, krypton, xenon, and methane and three binary mixtures: argon+krypton, argon+xenon, and krypton+xenon. The fluids are modeled by spherical Lennard-Jones pair-potentials, with paramete...

Under high pressure, krypton, one of the most inert elements is predicted to become sufficiently reactive to form a new class of krypton compounds; krypton oxides. Using modern ab-initio evolutionary algorithms in combination with Density Functional Theory, we predict the existence of several thermodynamically stable Kr/O species at elevated pressures. In particular, our calculations indicate t...

Line broadening of the hydrogen Balmer lines provides a sensitive measure of the number and energy of excited hydrogen atoms in a glow discharge plasma. The width of the 656.5 nm Balmer α line emitted from gas discharge plasmas having atomized hydrogen from pure hydrogen alone, hydrogen with magnesium or strontium, a mixture of 10% hydrogen and helium, argon, krypton, or xenon, and a mixture of...

The available data on the cross sections of electronimpact excitation of krypton 5s and 5p configuration levels out of the ground state are represented in convenient and compact form. The results are obtained by regression through all known published data related to this process. Keywords—Cross section, electron excitation, krypton, regression

A portable apparatus for the separation of krypton from environmental air samples was tested. The apparatus is based on the cryogenic trapping of gases at liquid nitrogen temperature followed by controlled releases at higher temperatures. The setup consists of a liquid nitrogen trap for the removal of H(2)O and CO(2), followed by charcoal-filled coils that sequentially collect and release krypt...

Hydrogenated amorphous carbon a-C:H films were prepared by plasma enhanced chemical vapor deposition using methane CH4 plus krypton Kr mixed atmosphere. The depositions were performed as function of the bias voltage and krypton partial pressure. The goal of this work was to study the influence of krypton gas on the physical properties of a-C:H films deposited on the cathode electrode. Krypton c...

Several new analyses of the martian atmosphere have been carried out with the mass spectrometer in the molecular analysis experiment. The ratios of abundant isotopes of carbon and oxygen are within 10 percent of terrestrial values, whereas nitrogen-15 is considerably enriched on Mars. We have detected argon-38 and set new limits on abundances of krypton and xenon. The limit on krypton is suffic...

In this paper, we show that Krypton atoms form a commensurate solid (CS) phase with a fractional coverage of one krypton atom per every four carbons on zigzag carbon nanotubes. This is a unique phase, different from the √ 3×√3R30◦ CS monolayer formed on graphite, which has a lower coverage of one krypton atom per every six carbons. Our prediction disagreeswith experiments that observe in nanotu...

Benchmark intensity ratio measurements of the energy loss lines krypton for excitation 4p61S0?4p55s[3/2]2, 4p55s[3/2]1, 4p55s?[1/2]0, and 4p55s?[1/2]1 transitions are reported, these being lowest electronic excitations krypton. The importance ratios as stringent tests theoretical electron scattering models noble gases is discussed, well role spin-exchange direct processes regarding angular depe...

Room-pressure flash-cryocooling of protein crystals is the standard way to reduce radiation damage during data collection. Typically, it is necessary to find cryoprotection conditions by trial and error, a process that is not always successful. Recently, a new method, high-pressure cryocooling, was developed that does not require penetrative cryoprotectants and typically yields very high qualit...