We studied structural relaxation in the bulk metallic glass forming alloy ${\mathrm{Zr}}_{46.8}{\mathrm{Ti}}_{8.2}{\mathrm{Cu}}_{7.5}{\mathrm{Ni}}_{10}{\mathrm{Be}}_{27.5}$ on different timescales and length scales, with emphasis supercooled liquid state. Using x-ray photon correlation spectroscopy, we determined microscopic time covering of more than two decades region, down to subsecond regim...

Macromolecular or polymeric liquids consist of polymer solutions, polymer melts, particle suspension fluids, and many biological fluids. Polymer solutions are made of polymers dissolved in solutions or solvent; polymer melts are molten polymers; particle suspension fluids consist of solid particles suspended in a matrix fluid which may be a viscous or viscoelastic fluid, blood flows consist of ...

We de ne a generic correlation function that quanti es the spatial correlation of single-particle displacements in liquids and amorphous systems. We evaluate this function using computer simulations of an equilibrium glass-forming liquid, and show that the displacements of particles are spatially correlated over a range that grows with decreasing temperature as the glass transition is approache...

By using the concepts of the short-range order (SRO) and middle-range order (MRO) characterizing structures, an attempt has been made to describe the glass forming ability (GFA) of liquid alloys. This includes the effect of more than two kinds of SRO in the liquid caused by the addition of second and third elements to a metallic solvent. The minimum solute concentration is related to the atomic...

We introduce a structural quantity to probe the glass transition. This quantity is a linear generalized compressibility which depends solely on the positions of the particles. We have performed a molecular dynamics simulation on a glass-forming liquid consisting of a two-component mixture of soft spheres in three dimensions. As the temperature is lowered (or as the density is increased), the ge...

The synthesis and physical properties, in particular electro-optic switching behavior, of 3-chloro-biphenyl-3',4-bis[4-[4-(3,7-dimethyloctyloxy)-phenyliminomethyl]] benzoate are reported. The compound exhibits an antiferroelectric tilted smectic liquid crystalline phase (Sm-CP) in a broad temperature range. Below 20 degrees C the sample goes over to a glassy state and no crystallization appears...