the preparation of polymer membrane selective to iron(ii) ion and its application to ion-selectiveelectrode is reported here. pvc membrane contains iron–selective n-phenylaza-15-crown-5 asionophore. the membrane electrode is highly selective to iron(ii) ion and exhibit good linearresponse over a wide concentration range of 1.0 × 10-2 to 1.0 × 10-6 m with nernstian slope of29.2 ± 0.6 mv per deca...

A three-dimensional computational fluid dynamics model of a proton exchange membrane fuel cell (PEMFC) with both gas distribution flow channels and Membrane Electrode Assembly (MEA) is developed. A set of conservation equation is numerically solved by developing a CFD code based on the finite volume technique and SIMPLE algorithm. In this research, some parameters like oxygen consumption, water...

a highly selective electrode for bromide ion based on aza pyrilium derivative as an excellentionophore is described.the sensor exhibits a good linear response with a slope of ( 60±1 ) mv per decadeover the concentration range of ( 1×10-3 – 9×10-6 m ) , and a detection limit of ( 3×10-6 m ) of bromideions .the electrode response is independent of ph in the range of(4.0 –9.5).selectivity coeffici...

a pvc membrane electrode based on 1-[({[(butylsulfunyl)carbothioyl]disulfanyl} carbothioyl)sulfanyl]butane as a suitable ion carrier for determination of lanthanum(iii) ion was prepared. this electrode revealedsuch a good selectivity toward la3+ ion over a wide variety of other metal ions. some experimental parametersuch as membrane composition, nature, and amount of plasticizer, the amount of ...

Nowadays, more and attention has been paid to flexible electrodes, which can be used make wearable devices so as monitor health signals, such those in ECG, EMG EEG. However, the contact impedance of many membrane electrodes is high due bad fit between sensors skin, or poor sensitivity caused by low conductivity. Therefore, we fabricated a skin-like conductive electrode via electroless silver pl...

the carrier facilitated transport of lithium picrate was studied using a series of non-cyclic polyethers containing different end groups and chain lengths through bulk liquid membrane (blm) and supported liquid membrane (slm) systems. the various membrane supports used are viz. ptfe, cellulose nitrate, and dialysis membrane and onion membrane. the amount of li+ transported depends upon the stru...

a new cesium ion selective pvc membrane based on parent calix [4] arene was developed for potentiometric determination of cesium in environmental samples. the electrode based on p-5,11,17,23tetra(tertbutyl) 25,26,27,28-tetrahydroxy calix[4]arene(thc) as ionophor ,dibutyl phthalate (dbp)as plasticizer ,sodium tetra phenyl borate(natpb)and oleic acid as lipophilic salt and additive showed the bes...

A new liquid membrane electrode for caffeine prepared from a solution of caffeine-picrylsulfonate ion-pair complex in n-octanol is developed. It exhibits Nernstian response in the range of w-·2 to 10M caffeine with a cationic slope of 59 mY/concentration decade. The electrode has a wide working pH range (5.59.5), fast response time (20 seconds1.5 minutes), stable response for at least 30 days a...