Cellulose acetate (CA) and Tween-20(T-20) are interacted and resulted as a supported liquid membrane system. The membrane potential was measured with uni-uni valent electrolyte, NaCl solutions using saturated calomel electrodes (SCEs).The effective fixed charge density of the membrane was determined by TMS method. Other important electrochemical parameters were calculated. Membrane adsorb-abili...

(The diagram gives, however, no indication of the hydrostatic pressure due to the liquid in the manometer tube, which is a necessary condition for equilibrium. For further details of the experiments Loeb's original papers and book s may be consulted.) AH and BH represent hydrogen electrodes; AK and BK, calomel electrodes connected to the solutions by saturated KC1. Loeb measured the potential d...

Copper oxide-based gas-diffusion electrodes (CuxO/GDEs) for CO2 electrocatalytic reduction are investigated in presence and absence of liquid electrolyte (liquid- gas-phase operations) terms (i) catalytic reactivity compact-design flow cells (with the located on two sides a Nafion membrane) (ii) situ electrochemical characterization by impedance spectroscopy (EIS), cyclic voltammetry (CV) chron...

this paper deals with the extraction of l-theanine containing aliquat 336 as a carrier and cyclohexane as solvent across bulk liquid membrane. the optimum operation condition are as follows: extraction time of 150 min, initial concentration of theanine in the feed phase is 1.8 g/l, the carrier concentration is 0.5 m, the ion of the receiving phase is 0.2 m nacl of na2hpo4-nah2po4 buffer solutio...

Three new electrodes were prepared by incorporating two different charge-transfer complexes and amino crown ether into plasticized PVC membranes. The electrodes showed Nernstian response to triiodide ion over the activity range from 1.0 x 10(-5) to 1.0 x 10(-1) mol x L(-1) with detection limits at approximately 1.0 x 10(-6) mol x L(-1). The resulting electrodes have fast response times (20-30 s...

the kinetics of the potassium thiocyanate transport mediated by dicyclohexyl-18-crown-6 (l) through a bulk liquid membrane is studied experimentally and theoretically. the proposed model is based on the assumption of a pure diffusion of the complex salt [k·l]+scn¯ through the liquid membrane stagnant films at the interfaces. it illustrates the connection between liquid-liquid extraction equilib...

The carrier facilitated transport of lithium picrate was studied using a series of non-cyclic polyethers containing different end groups and chain lengths through Bulk Liquid Membrane (BLM) and Supported Liquid Membrane (SLM) systems. The various membrane supports used are viz. PTFE, cellulose nitrate, and dialysis membrane and onion membrane. The amount of Li+ transported depends upon the stru...

Hydrogen peroxide (H2O2) plays a pivotal role in various industrial applications [1]. It is an essential mediator in pharmaceutical, clinical, and environmental research. In addition, it is a byproduct of highly selective oxidases and an important contaminant in several industrial products and wastes [2]. Therefore, a reliable and economical method for the determination of H2O2 is of great sign...

Trilayer polypyrrole microactuators that can operate in air have previously been developed. They consist of two outer layers of the electroactive polymer polypyrrole (PPy) and one inner layer of a porous poly(vinylidene flouride) (PVDF) membrane containing a liquid electrolyte. The two outer layers of PPy are each connected with gold electrodes and separated by the porous PVDF membrane. This mi...