Magnetic C-C@Fe3O4 hollow microspheres were prepared by using aerosol-based Fe3O4@C-SiO2 core-shell particles as templates. The magnetic double-shelled microspheres efficiently worked as carriers to load Pt nanoparticles, thus making the catalyst recyclable and reusable.

ω-Transaminase (ω-TA) as a kind of important biocatalyst is widely used in preparation of chiral intermediates. In this paper, a magnetic PVA-Fe3O4 nanoparticles was prepared and employed on immobilization of ω-TA to reduce the cost, increase reusability and enhance stability. The prepared magnetic PVA-Fe3O4 nanoparticles were characterized by transmission electron microscope (TEM), X-ray diffr...

in this research controlled coating of magnetite (fe3o4) nanoparticles with sio2 was investigated. the fe3o4 nanoparticles were synthesized via chemical co-precipitation and then coated by silica according to stober method. effects of tetra ethyl ortho silicate (teos) concentration and ethanol to teos on the coating thickness were investigated. x-ray powder diffraction, fourier transform infrar...

Novel-morphological Fe3O4 nanosheets with magnetochromatic property have been prepared by a modified solvothermal method. Such nanosheets could form one-dimension photonic crystal under an external magnetic field. The Fe3O4 nanosheets suspension could strongly diffract visible light and display varied colors with changing the intensity of the magnetic field. The photonic response is rapid, full...

Magnetic nanoparticles with attractive optical properties have been proposed for applications in such areas as separation and magnetic resonance imaging. In this paper, a simple and novel fluorescent sensor of Zn2+ was designed with 3,5-di-tert-butyl-2-hydroxybenzaldehyde [DTH] covalently grafted onto the surface of magnetic core/shell Fe3O4@SiO2 nanoparticles [NPs] (DTH-Fe3O4@SiO2 NPs) using t...

In the last decade, nanobiotechnology has evolved rapidly with an extensive impact on biomedical area. In order to improve bioavailability and minimize adverse effects, drug delivery systems based on magnetic nanocomposites are under development mainly for cancer imaging and antitumor therapy. In this regard, pH sensitive core-shell magnetic nanoparticles (NPs) with accurate controlled size and...

We report herein an investigation into dynamic magnetic clustering that occurs during immunoassays as biofunctionalized magnetic nanoparticles (BMNs) become associated with biotargets. We measure the dynamic effective relaxation time τeff(t) and use scanning electron microscopy (SEM) and transmission electron microscopy (TEM) to investigate the C-reactive protein (CRP) as it associates with the...

We present measurements of the spin and orbital magnetic moments of Fe3O4 by using SQUID and magnetic circular dichroism in soft x-ray absorption. The measurements show that Fe3O4 has a noninteger spin moment, in contrast to its predicted half-metallic feature. Fe3O4 also exhibits a large unquenched orbital moment. Calculations using the local density approximation including the Hubbard U metho...

This work reports a hard self-template method to synthesize core/shell like Fe3O4@C microparticles, in which the Pd nanocrystals can be alternatively incorporated into the carbon shells. The Fe3O4@polyaniline core/shell microspheres were first synthesized as the precursor by in situ polymerization of aniline onto the surface of the Fe3O4 microspheres. In a subsequent carbonization of the precur...

A magnetic chitosan-polypyrrole-magnetite (Cs-PPy-Fe3O4) nanocomposite is prepared in a simple one-step method via in situ chemical polymerization of pyrrole using anhydrous FeCl3 as an oxidant in the presence of Cs. Magnetic Fe3O4 nanoparticles of size in the range of 10-20 nm are successfully introduced into the Cs-PPy matrix. Adsorption of an anionic dye (acid green 25, AG) from aqueous solu...