Industrial purification of propylene and ethylene requires cryogenic distillation selective hydrogenation over palladium catalysts to remove propane, ethane and/or trace amounts acetylene. Here, we report the excellent separation equimolar mixtures propylene/propane ethylene/ethane, a 1/100 mixture acetylene/ethylene by highly robust microporous material, MFM-520, under dynamic conditions. In s...

To improve the CO2/N2 separation performance, mixed-matrix carbon molecular sieve membranes (mixed-matrix CMSMs) were fabricated and tested. Two carbon-based fillers, graphene oxide (GO) activated (YP-50F), separately incorporated into two polymer precursors (Matrimid® 5218 ODPA-TMPDA), resulting CMSMs demonstrated improved CO2 permeability. The improvement afforded by YP-50F was more substanti...

Mixed matrix membranes (MMM) incorporating metal-organic framework (MOF) fillers have gained increasing attention in addressing environmental and sustainability challenges. Hierarchical materials combining pore sizes of different length scales are expected to facilitate molecular diffusion mass transfer for the optimization catalysis separation processes. Herein, a novel preparation method hier...