Clomipramine hydrochloride, active component of an antidepressant drug, was determined in the pharmaceutical formulation by two kinds of potentiometric sensor; a PVC membrane sensor and a carbon paste electrode modified by MWCNTs and ionic liquid. Both sensors were corporated with clomipramine-tetraphenylborate ion-pair complex and they respond based on ion exchange mechanism. The best PVC memb...

This mini review describes the results regarding the voltammetric determination of micromolar, submicromolar and nanomolar concentrations of various fluoroquinolones antibacterial agents using both traditional hanging mercury drop electrode, carbon paste electrode, glassy carbon paste electrode and chemically modified electrodes. We concentrate on the interaction of quinolones with DNA in solut...

in this study, a sodalite nanozeolite was synthesized and characterized by x-ray diffraction (xrd) and scanning electronic microscopy (sem). following the morphology evolution of the sodalite nanozeolite in the sem images illustrates the formation of the spherical particle with a size between 60 and 80 nm. then, carbon paste electrode (cpe) was modified by sodalite nanozeolite and ni2+ ions. th...

a novel modified ni-zsm-5 nanozeolite was fabricated via an organic template-free hydrothermal route. the average particle size of ni-zsm-5 nanozeolite was calculated to be 85 nm by scanning electronic microscopy. then, carbon paste electrode (cpe) was modified by ni-zsm-5 nanozeolite and ni2+ ions were then incorporated to the nanozeolite matrix. electrochemical behavior of this electrode was ...

Carbon paste electrode modified with cobalt impregnated zeolite was prepared by mixing of cobalt_zeolite (Co_Z) and graphite powder with different percent. The electrochemical oxidation of cefixime at such electrodes was investigated using the cyclic voltammetric and amperometric techniques. It is not electrochemically active towards cefixime oxidation in 0.1 M phosphate buffer solution (pH=7) ...

An analytical method has been described for the determination of mercury using a carbon paste electrode. Conditions for the preparation of the carbon paste electrode were optimized for low background current in order to use it for the determination of ultra trace levels of mercury. The carbon paste electrode was found to be a good electrode material for the determination of mercury. The optimiz...

Electrochemical behaviors of methocarbamol (MET) at the bare carbon paste electrode (CPE), acetylene black (AB) modified carbon paste electrode (AB/CPE), an ionic liquid 1-Benzyl-3Methylimidazole hexafluorophosphate ([BnMIM]PF6) modified carbon paste electrode ([BnMIM]PF6/ CPE) and AB-[BnMIM]PF6 modified carbon paste electrode (AB-[BnMIM]PF6/CPE) in PBS (pH = 6.8) were investigated by cyclic vo...

Rapid and facile preparation of the cheap modified electrode materials is an important parameter in development of the efficient electrochemical sensor for industrial scale production and mass-market usage. In the present work, the carbon paste electrode modified with multi-walled carbon nanotubes (MWCNTs) was prepared for sensitive determination of lead (Pb) ion in the presence of bismuth (Bi)...

In this paper, a nanostructured modified electrode was fabricated by incorporating of 2,2′-[1,9-nonanediylbis(nitriloethylidyne)]-bis-hydroquinone (NNH) as a newly synthesized modifier and TiO2 nanoparticles to the carbon paste (MTCPE) and then was used for the electroanalysis of epinephrine (EP). The electrochemical studies were carried out by using cyclic voltammetry, chronoamperom...

A chemically modified graphene paste electrode was prepared by incorporating appropriate amounts of graphene in a paste mixture, followed by electrodepositing Prussian blue (PB) and coating chitosan on the electrode surface. The electrode was able to bind ssDNA, and gave a better voltammetric response for complement DNA than did ordinary carbon paste electrodes. The response of the electrode wa...