Decreasing the dimensions of ionic conductors to the nanoscale has enabled the realization of new electrochemical devices integrated on Si-based and other microsystems. These comprise fast ionic conducting electrolytes for energy-applications such as micro-fuel cells [ 1,2 ] and batteries, [ 3 ] gas conversion/reformation catalysts, [ 4,5 ] sensors, [ 6 ] and for redox-reaction based resistive ...

This paper investigates a nano-enhanced wireless sensing framework for dissolved oxygen (DO). The system integrates a nanosensor that employs cerium oxide (ceria) nanoparticles to monitor the concentration of DO in aqueous media via optical fluorescence quenching. We propose a comprehensive sensing framework with the nanosensor equipped with a digital interface where the sensor output is digiti...

The nanoscience and nanotechniques have brought with new chance for new applications of some traditional materials, for instance, ceria-based materials, which are of great interest due to their wide applications, in particular, as redox or oxygen storage promoters in the three-way catalysts, catalysts for H(2) production from fuels, and solid state conductors for fuel cells. We highlight here c...

Engineered nanoscale ceria is used as a diesel fuel catalyst. Little is known about its mammalian central nervous system effects. The objective of this paper is to characterize the biodistribution of a 5-nm citrate-stabilized ceria dispersion from blood into brain and its pro- or antioxidant effects. An approximately 4% aqueous ceria dispersion was iv infused into rats (0, 100, and up to 250 mg...

PURPOSE Ceria engineered nanomaterials (ENMs) have current commercial applications and both neuroprotective and toxic effects. Our hypothesis is that ceria ENMs can associate with brain capillary cells and/or cross the blood-brain barrier. METHODS An aqueous dispersion of ∼5 nm ceria ENM was synthesized and characterized in house. Its uptake space in the Sprague Dawley rat brain was determine...

The thermodynamic properties of surface ceria were investigated through equilibrium isotherms determined by flow-titration and coulometric-titration measurements on high-surface-area ceria and ceria supported on La-modified alumina (LA). While the surface area of pure ceria was found to be unstable under redox conditions, the extent of reduction at 873 K and a P(O2) of 1.6x10-26 atm increased w...

The CO preferential oxidation (PrOx) is one of the critical steps in hydrogen production and purification for Polymer Electrolyte Membrane Fuel Cell (PEMFC). This reaction was investigated in the presence of excess hydrogen over Cu/CeO2, Pt/CeO2 and Cu-Pt/CeO2 catalysts. The ceria supports was prepared via precipitation method and Cu-Pt/CeO2 catalyst was synthesized by sequential impregnation o...

Cerium oxide, or ceria (CeO x : x = 1.5 to 2), has been widely used as a heterogeneous catalyst. Ceria has several properties make it high catalytic active: the fluctuating valence of cerium, the high oxygen storage capacity and high oxygen mobility in the nonstoichiometric ceria. With the high abundance of cerium on earth crust, ceria is a highly effective alternative of the noble metal cataly...

The cytotoxicity of ceria ultimately lies in its electronic structure, which is defined by the crystal structure, composition, and size. Despite previous studies focused on ceria uptake, distribution, biopersistance, and cellular effects, little is known about its chemical and structural stability and solubility once sequestered inside the liver. Mechanisms will be presented that elucidate the ...