A hetero-nanostructured photoanode with enhanced near-infrared light harvesting is developed for photo-electrochemical cells. By spatially coating upconversion nanoparticles and quantum dot photosensitizers onto TiO2 inverse opal, this architecture allows direct irradiation of upconversion nanoparticles to emit visible light that excites quantum dots for charge separation. Electrons are injecte...

Photoactive in one step! A nanocomposite water-oxidation photocatalyst was assembled by a straightforward and one-step spin-coating procedure of a Ti- and Ni-containing molecule on nanostructured WO3. The photoanode oxidizes water to O2 with good activity and stability in alkaline solution, and thereby features light absorption, charge separation and water-oxidation catalysis (see scheme).

Nanostructured ZnO thin films were prepared by sol-gel dip coating technique. Zinc acetate and ammonium hydroxide were used as precursors and ethanol was as solvent. Ammonium hydroxide (NH4OH) solution was added drop-wise under vigorous stirring to obtain the sol-gel of different pH (varying from 6.9 to 7.2). ZnO thin films were obtained by dipping the glass substrates for few seconds and then ...

Coating Ti-based implants with bioactive materials promotes joining between the prostheses and the bone as well as increasing long-term implant stability. In the present work, the interface between Ti-6Al-4V and bioactive silicate glass coatings, prepared using a simple enameling technique, is analyzed. High-resolution transmission electron microscopy of the glass/alloy interface shows the form...

A nanostructured hydroxyapatite (HA) feedstock was thermally sprayed on Ti–6Al–4V substrates via high velocity oxy-fuel (HVOF process). The particle temperature and velocity for the HA particles in the HVOF jet were monitored during spraying and found to be 1826± 346 ◦C and 638± 82 m/s, respectively. The bioactivity of the coating was investigated in a simulated physiological environment, as an...

Phase change cooling schemes involving passive heat spreading devices, such as heat pipes and vapor chambers, are widely adopted for thermal management of high heat-flux technologies. In this study, carbon nanotubes (CNTs) are fabricated on a 200 lm thick sintered copper powder wick layer using microwave plasma enhanced chemical vapor deposition technique. A physical vapor deposition process is...

limn2o4 spinel cathode materials have been successfully synthesized by solid-state reaction. surface of these particles were modified by nanostructured lifepo4 via sol gel dip coating method. synthesized products were characterized by thermally analyzed by thermogravimetric and differential thermal analysis(tg/dta), x-ray diffraction (xrd), scanning electron microscopy (sem), and energy dispers...

Nanostructured alumina thin films were coated on stainless steel by Sol-Gel dip coating method. In order to prevent crack formation, Al2O3 films were kept in a solvent bath immediately after coating to reduce the rate of drying. Effects of calcination temperature and withdrawal speed on structural properties were analyzed using XRD and SEM. Topography and thickness of coat...

In this paper, the possibility of mechanical coating of aluminum with either Ni or SiC using planetary ball mill was studied. The Al substrate was fixed inside of the vial lid of a planetary ball mill filled with milling balls and starting powder. The phase analysis and crystallite size measurement of the coatings were carried out using X-ray diffraction (XRD) method. Scanning electron micro...