The lifetime of Er3+ in silicon-rich silicon oxide has been reported with quite widely varying values ranging from 9 ms to 2 ms. In this work, we consider the direct impact of silicon nanoclusters on the erbium radiative lifetime, and show that it is a function of the silicon nanocluster size, and also the erbium proximity to the nanocluster.

We experimentally observe magnetic resonance in the visible frequency region from self-assembled silver nanocluster metamaterials. Extensive numerical modeling studies were conducted to find the optimal nanocluster dimensions. Self-assembly of silver nanoparticles coated with nanoscale silica coating was then performed on polymer templates fabricated by laser interference lithography. The nanoc...

A continuum, post-deposition mesoscopic model of a Moir\'e-regulated self-assembly metal nanoclusters on twisted bilayer graphene is presented. Quasi-two-dimensional nanocluster-like steady states at low adsorbate coverage are analytically determined for Pt, Ni, and Pb adsorbates, pointing that self-assemble the Moir\'e cells centers. This followed by computations dynamics. Differences in effic...

An effective method for ultrafast magnetization reversal of nanoclusters is suggested. The method is based on coupling a nanocluster to a resonant electric circuit. This coupling causes the appearance of a magnetic feedback field acting on the cluster, which drastically shortens the magnetization reversal time. The influence of the resonator properties, nanocluster parameters, and external fiel...

We report the discovery of a DNA sequence that templates a highly stable fluorescent silver nanocluster. In contrast to other DNA templated silver nanoclusters that have a relatively short shelf-life, the fluorescent species templated in this new DNA sequence retains significant fluorescence for at least a year. Moreover, this new silver nanocluster possesses low cellular toxicity and enhanced ...

The theoretically predicted volcano plot for hydrogen production shows the best catalyst as the one that ensures that the hydrogen binding step is thermodynamically neutral. However, the experimental realization of this concept has suffered from the inherent surface heterogeneity of solid catalysts. It is even more challenging for molecular catalysts because of their complex chemical environmen...

In this thesis, we show the results of the molecular dynamics (MD) simulations of the collisions between nanoscale objects such as (i) nanocluster depositions on a crystalline surface, (ii) nanocluster depositions on a free-standing graphene, and (iii) oblique impacts of two nanoclusters. The aim of this thesis is to analyze the mechanics of nanoscale objects and to explain the results of the m...

The chemical and physical properties of nanoclusters largely depend on their sizes and shapes. This is partly due to finite size effects influencing the local electronic structure of the nanocluster atoms which are located on the nanofacets and on their edges. Here we present a thorough study on graphene-supported Rh nanocluster assemblies and their geometry-dependent electronic structure obtai...

Noble metal nanoclusters are ultrasmall nanomaterials with tunable properties and huge application potential; however, retaining their enhanced functionality is difficult as they readily lose their properties without stabilization. Here, we demonstrate a facile synthesis of highly photostable silver nanoclusters in a polymer thin film using visible light photoreduction. Furthermore, the differe...

This work reports on the fabrication of tin nanoclusters by sputtering and inert-gas condensation inside an ultrahigh vacuum compatible system. This technique allows to fine tune the size and yield of nanoclusters by controlling the nanocluster source parameters. The produced nanoclusters are deposited on SiO2/Si substrate with pre-formed electrical electrodes to produce a nanocluster device. T...