Aromatic compounds are characterised by the presence of a ring current when in a magnetic field. As a consequence, current density maps are used to assess (the degree of) aromaticity of a compound. However, often a more discrete set of so-called Nucleus Independent Chemical Shift (NICS) values is used that is derived from the current density. It is shown here that there is no simple one-to-one ...

Noninvasive cortical stimulation (NICS) can produce analgesic effects by means of repetitive transcranial magnetic stimulation or transcranial direct current stimulation (tDCS). Such effects have been demonstrated on chronic ongoing pain, as in acute provoked pain. The investigation of induced changes in the perception of experimental pain by NICS could help clinicians and researchers to better...

The nucleus-independent chemical shifts (NICS) and electron density profiles along the inner and outer regions defined by the two stacked aromatic rings of [2.2]paracyclophane have been analyzed and compared to those of free benzene and p-xylene and benzene dimers taken as reference models. It is found that stacked aromatic rings show a reduction of the NICS indicator of aromaticity as compared...

As compared to classical organic aromatic compounds, the evaluation of aromaticity in all-metal and semimetal clusters is much more complex. For a series of these clusters, it is frequently found that different methods used to discuss aromaticity lead to divergent conclusions. For this reason, there is a need to evaluate the reliability of the different descriptors of aromaticity to provide cor...

A series of monocyclic planar inorganic compounds have been optimized at the B3LYP/6-311+G* level. GIAO-B3LYP nucleus-independent chemical shifts (NICS) profiles calculated in the perpendicular direction of each ring show that the series of analyzed compounds can be classified in three groups according to their aromatic, non-aromatic or antiaromatic character. Our results suggest exercising cau...

Invasive non-indigenous crayfish species (NICS) are a major threat to the existence of native populations in European freshwater ecosystems. The discovery signal Pacifastacus leniusculus, marbled Procambarus virginalis, and spiny-cheek Faxonius limosus Estonia has increased risk extinction Estonia’s only species, noble Astacus astacus. aim this study was give an overview status, distribution, i...

Recent work in low-latency, high-bandwidth communication systems has resulted in building user–level Network Interface Controllers (NICs) and communication abstractions that support direct access from the NIC to applications virtual memory to avoid both data copies and operating system intervention. Such mechanisms require the ability to directly manipulate user–level communication buffers for ...

The Institute of Social Studies is Europe's longest-established centre of higher education and research in development studies. Postgraduate teaching programmes range from six-week diploma courses to the PhD programme. Research at ISS is fundamental in the sense of laying a scientific basis for the formulation of appropriate development policies. The academic work of ISS is disseminated in the ...

Neurosphere formation is commonly used as a surrogate for neural stem cell (NSC) function but the relationship between neurosphere-initiating cells (NICs) and NSCs remains unclear. We prospectively identified, and isolated by flow cytometry, adult mouse lateral ventricle subventricular zone (SVZ) NICs as Glast(mid)EGFR(high)PlexinB2(high)CD24(-/low)O4/PSA-NCAM(-/low)Ter119/CD45(-) (GEPCOT) cell...