a simple and rapid method for the determination of 137ba isotope abundances in water samples by inductively coupled plasma-optical emission spectrometry (icp-oes) coupled with least-squares support vector machine regression (ls-svm) is reported. by evaluation of emission lines of barium, it was found that the emission line at 493.408 nm provides the best results for the determination of 137ba a...

Number of latents The same number of factors will be extracted for PLS responses as for PLS factors. The researcher must specify how many latents to extract (in SPSS the default is 5). There is no one criterion for deciding how many latents to employ. Common alternatives are: 1. Cross-validating the model with increasing numbers of factors, then choosing the number with minimum prediction error...

Partial least squares (PLS) was not originally designed as a tool for statistical discrimination. In spite of this, applied scientists routinely use PLS for classification and there is substantial empirical evidence to suggest that it performs well in that role. The interesting question is: why can a procedure that is principally designed for overdetermined regression problems locate and emphas...