This study investigates the effects of calcium carbonate (CaCO(3)) nanoparticles on the mechanical and thermal properties and surface morphology of polycaprolactone (PCL)/chitosan nanocomposites. The nanocomposites of PCL/chitosan/CaCO(3) were prepared using a melt blending technique. Transmission electron microscopy (TEM) results indicate the average size of nanoparticles to be approximately 6...

A bioactive composite of nano calcium-deficient apatite (n-CDAP) with an atom molar ratio of calcium to phosphate (Ca/P) of 1.50 and poly(ɛ-caprolactone)-poly(ethylene glycol)-poly(ɛ-caprolactone) (PCL-PEG-PCL) was synthesized, and a composite scaffold was fabricated. The composite scaffolds with 40 wt% n-CDAP contained well interconnected macropores around 400 μm, and exhibited a porosity of 7...

Electrospinning is a process by which fibers with micron to nanometer diameters can be obtained from an electrostatically driven jet of polymer solution. These fibers have a high surface area to volume ratio, which have numerous applications in biomedical implants such as total hip implant, dental implant. The present study is based on the hypothesis that the differences of the surface properti...

In this study, vascular stents were fabricated from poly (lactide-ɛ-caprolactone)/collagen/nano-hydroxyapatite (PLCL/Col/nHA) by electrospinning, and the surface morphology and breaking strength were observed or measured through scanning electron microscopy and tensile tests. The anti-clotting properties of stents were evaluated for anticoagulation surfaces modified by the electrostatic layer-b...

Optically transparent membranes from bacterial cellulose (BC)/polycaprolactone (PCL) have been prepared by impregnation of PCL acetone solution into dried BC membranes. UV-Vis measurements showed an increase on transparency in BC/PCL membrane when compared with pristine BC. The good transparency of the BC/PCL can be related to the presence of BC nanofibers associated with deposit of PCL nano-si...

Poly(glycerol sebacate) (PGS) has increasingly become a desirable biomaterial due to its elastic mechanical properties, biodegradability, and biocompatibility. Here, we report microfibrous core−shell mats of polycaprolactone (PCL)−PGS prepared using wet−wet coaxial electrospinning. The anticoagulant heparin was immobilized onto the surface of these electrospun fiber mats, and they were evaluate...

a new simple and reliable method for rapid and selective extraction and determination of trace levels of zn(ii) ion is developed. zn(ii) ions are adsorbed quantitatively during passage of aqueous samples through pet-aa/aam nano fiber modified. almost all matrix elements were found to pass through the nano fiber to drain. modified poly (ethylene terephthalate)-grafted-acrylic acid/acryl amide na...

a simple method has been developed for the preconcentration of copper(ii) based on the adsorption of its modified nano polyacrylonitrile fiber. modified nano polyacrylonitrile fiber (panf) was prepared by adding of acrylic fibers to msethanolamine (mma) with different concentration solutions. the stability of a chemically modified nano polyacrylonitrile fiber especially in concentrated hydrochl...

AIMS The matrix metalloproteinase (MMP) 2/9, also known as collagenases IV and gelatinases A/B, play a key role in cancer invasion and metastasis. However, the clinical trials of the MMP inhibitors (MMPIs) ended up with disappointing results. In this paper, we synthesized a gelatinase-responsive copolymer (mPEG-PCL) by inserting a gelatinase cleavable peptide (PVGLIG) between mPEG and PCL block...