The 13-atom metal clusters of fcc elements (Al, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au) were studied by density functional theory calculations. The global minima were searched for by the ab initio random structure searching method. In addition to some new lowest-energy structures for Pd13 and Au13, we found that the effective coordination numbers of the lowest-energy clusters would increase with the ra...

Trimetallic Au24-xAgxPd and tetrametallic Au24-x-yAgxCuyPd clusters were synthesized by the subsequential metal exchange reactions of dodecanethiolate-protected Au24Pd clusters. EXAFS measurements revealed that Pd, Ag, and Cu dopants preferentially occupy the center and edge sites of the core, and staple sites, respectively. Spectroscopic and theoretical studies demonstrated that the synergisti...

Micronized and nano-copper (Cu)-based and arsenic and chromium-free systems have received much attention for wood protection in recent years. Because they have different fixation, and micro-distribution properties, such copper systems may be more or less subject to release using known remediation methods than soluble forms of Cu. This study evaluated Cu recovery from wood treated with micronize...

Nano-sized, nonreacting, noncoarsening ZrO2 particles reinforced Sn–3.0 wt%Ag–0.5 wt%Cu composite solders were prepared by mechanically dispersing ZrO2 nano-particles into Sn–Ag–Cu solder. The interfacial morphology of unreinforced Sn–Ag–Cu solder and solder joints containing ZrO2 nano-particles with Au/Ni metallized Cu pads on ball grid array (BGA) substrates and the distribution of reinforcin...

the selective reduction of oximes with sodium borohydride (nabh4) in the presence of nano cu and charcoal was investigated. cu nanoparticles are widely used as catalysts; efficacious catalyst: copper and copper alloy nanometer feature high efficacy and selectivity, and can be used as catalyst in some reactions. we have shown that nabh4 in the presence of charcoal is an efficient protocol for th...

In this research work, copper (Cu), palladium (Pd) and their bimetallic palladium@ copper (Pd@Cu) nanoparticles were synthesized using trisodium citrate as a stabilizing agent using the known chemical reduction method. The synthesized Cu, Pd and Pd@Cu nanoparticles were characterized by the ultraviolet-visible spectroscopy, scanning electron microscopy and X-ray diffraction spectroscopy, respec...

The structural changes in electrodeposited palladium (Pd) films with desorption of co-deposited hydrogen were investigated, and the existing states Pd film analyzed. from an alkaline bath consisted (II) chloride, ammonium citric acid. Two pronounced peaks at around 500 K 880 observed thermal spectrum as-deposited film. For lower concentrations, lattice contraction proceeded concurrently room te...

Trends in oxygen reduction activity of Pd/Cu bimetallic random alloy nanoparticles are determined with calculations of oxygen binding for a range of compositions. A reduction in the average oxygen binding is found as Cu is added to Pd, indicating an increase in catalytic activity up to a peak at 1:1 Pd/Cu ratio. Calculations show that Cu reduces the Pd-O binding energy and Pd increases the Cu-O...

ed: Pt-based alloys have recently triggered a lot of attentions due to their important potential industrial applications. They provide great opportunities for the development of low-cost and high-performance fuel-cell catalysts. Many studies have already pointed out the excellent physico-chemical properties of Pt-based alloys, intimately related to their internal structure. Great efforts have b...

An energetic micro-initiator through integrating Al/Ni nano-multilayers with Cu film bridge was investigated in this study. The Cu film bridge was initially fabricated with wet etching, and Al/Ni nano-multilayers were alternately deposited on the surface of Cu film bridge by magnetron sputtering. The periodic layer structure of Al/Ni nano-multilayers was verified by scanning electron microscopy...