The aim of this work is to illustrate the structural and parametric optimization of continuous hybrid distillation-pervaporation process with different configurations such as series, parallel, and series-parallel arrangement of pervaporation modules in the pervaporation network, and to propose a generalized methodology for difficult separations. A superstructure representation of hybrid process...

In this work, poly (ether-block-amide) (PEBA)/ceramic hollow fiber (HF) composite membranes with high flux were prepared by dip-coating the ceramic hollow fiber with PEBA polymer solution for pervaporation (PV). The membrane fabrication was optimized by finely tailoring the coating parameters such as the viscosity and concentration of PEBA coating solution, which made the pervaporation flux as ...

Molecular sieving MFI-type zeolite membranes were prepared by a secondary growth method without using an organic template. Silicalite membranes with intercrystalline pores minimized or eliminated were obtained by this synthesis method which avoids the template removal step. The silicalite membrane exhibits molecular sieving characteristics with pervaporation separation factor for p-xylene to o-...

This work focuses on modelling, simulation and process analysis of hybrid membrane separations namely on distillation and pervaporation. Such hybrid process can be applied for the separation of multicomponent azeotropic mixtures without the use of entrainer. Its application is illustrated by the separation of a non-ideal ternary mixture of acetone, isopropanol and water. The extended abstract d...

Mass transfer phenomenon that occurs in the pervaporation process when applied to the microemulsion breakdown, was confirmed by the results of inverse gas chromatography. The stationary phase for this study was polydimethylsiloxane (PDMS), a hydrophobic polymer employed as a membrane in the pervaporation technique. The retention times of the different molecule probes (toluene, cyclohexane, and ...

In the chemical industry, process intensification is needed to meet important goals such as sustainable and eco-friendly processes. For esterification reaction the “produce more with less pollution” objective can be achieved by coupling reaction and separation in a so called integrated process. In this work a model for describing the esterification reaction of ethyl acetate in pervaporation mem...

Pervaporation has a high potential for separating miscible solutions, particularly azeotropic mixtures. However, mass transfer limitations have long been common concern in pervaporation device design. Therefore, this work, we design static mixer-based using water–ethanol separation as model system and further develop computational fluid dynamics tools to investigate systematically all the influ...

A review concerning pervaporation and vapor permeation membrane separation techniques used to separate liquid mixtures, is presented. Examples of polymers for membrane preparation as well as performance parameters of pervaporation and vapor permeation membranes are described. The second part of the paper presents applications of pervaporation and vapor permeation in environmental protection. At...

As part of a Department of Defense project, the US Environmental Protection Agency was responsible for designing, building and field operating a pilot-scale pervaporation unit. The field site was an active dry cleaning facility on the grounds of Marine Corps Base Camp Lejeune in Jacksonville, NC. The overall goal of the project was to remove tetrachloroethylene (PCE) from the soil beneath the d...

Ethanol-water concentration profiles in cellulose acetate membranes were measured under steady-state pervaporation conditions. Knowledge of these profiles leads to a better understanding of the diffusion process during pervaporation. The concentration profiles were determined by a film-stack method, using three to six layers. It is shown that permeation of ethanol-water mixtures proceeds in a c...