The reduction of carbon dioxide to fuels and chemicals can be accomplished by the use of electrocatalysts of the platinum group metals. Worthwhile products include carbon monoxide, formate, methanol, methane, oxalate and even higher hydrocarbons depending on the catalyst type and environment. Three classes of electrocatalysts have been identified: catalytic metal sugaces, monomeric solution com...

Objectives • Elucidate rates and mechanisms of the degradation of polymer electrolyte fuel cell (PEFC) platinum electrode performance – Effect of electrolyte, potential (holding and cycling), time, and temperature • Develop non-platinum cathode electrocatalysts for PEFCs – Transition metal carbides and nitrides – Bi-metallic systems – Metal centers attached to electron-conducting polymer backbones

Currently, platinum-based electrocatalysts show the best performance for hydrogen evolution. All hydrogen evolution reaction catalysts should however obey Sabatier's principle, that is, the adsorption energy of hydrogen to the catalyst surface should be neither too high nor too low to balance between hydrogen adsorption and desorption. To overcome the limitation of this principle, here we choos...

Pt/CeO2/C electrocatalysts in different compositions were prepared and their structural characteristics activities for ethanol oxidation alkaline media evaluated. In the presence of CeO2, an increase platinum particle size was observed. XANES measurements indicated that Pt d-band vacancies increased with increasing CeO2 amounts. For first time, decrease electro activity described to electronic ...

We report a novel method for fabricating a highly sensitive chemical sensor based on a ZnO nanorod array that is epitaxially grown on a Pt-coated Si substrate, with a top-top electrode configuration. To practically test the device, its O(2) and NO(2) sensing properties were investigated. The gas sensing properties of this type of device suggest that the approach is promising for the fabrication...

Replacing platinum by a less precious metal such as palladium, is highly desirable for lowering the cost of fuel-cell electrocatalysts. However, the instability of palladium in the harsh environment of fuel-cell cathodes renders its commercial future bleak. Here we show that by incorporating trace amounts of gold in palladium-based ternary (Pd6CoCu) nanocatalysts, the durability of the catalyst...

The electrocatalysts utilized as the prospective electrodes in fuel cells and high efficient energy conversion devices require both the interconnected channels for efficient electrolyte transportation and the superior catalytic activity with long service life. In this work, nanoporous gold with the rigid skeletons in three dimensions is partially decorated by porous platinum shell containing na...

To understand the interaction between Pt and surface oxygenated species in electrocatalysis, this paper correlates the electrochemistry of atomic oxygen on Pt formed in the gas phase with electrochemically generated oxygen species on a variety of single-crystal platinum surfaces. The atomic oxygen adsorbed on single-crystalline Pt electrodes, made by thermal dissociation of molecular oxygen, is...

Gold-platinum nanowires are proposed as electrocatalysts for a real-time nonenzymatic impedancimetric detection of glucose. The electrochemical behavior of the obtained platform toward electrocatalytic oxidation of glucose, including a proposal for the detection mechanism, is shown.

Platinum-cored ferritins were synthesized as electrocatalysts by electrochemical biomineralization of immobilized apoferritin with platinum. The platinum cored ferritin was fabricated by exposing the immobilized apoferritin to platinum ions at a reduction potential. On the platinum-cored ferritin, oxygen is reduced to water with four protons and four electrons generated from the anode. The ferr...