This study unambiguously confirms hydrolysis using cutinase of the persistent synthetic polymer poly(ethylene terephthalate), the most important synthetic fiber in the textile industry by direct measurement and identification of the different hydrolysis products. In this aqueous heterogeneous system, dissolved cutinase from Fusarium solani pisi acts on different solid poly(ethylene terephthalat...

A yellow, alkali-clearable azo disperse dye containing a carboxylic ester moiety was readily synthesized from the reactant p-aminobenzoic acid by successive diazotization, coupling reaction, chlorination and esterification with ethanol. Then its molecular structure was characterized by FTIR, H NMR, C NMR, mass spectrometry and elemental analysis. The synthesized dye and a similar control dye co...

We describe the organocatalytic depolymerization of poly(ethylene terephthalate) (PET), using a commercially available guanidine catalyst, 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD). Postconsumer PET beverage bottles were used and processed with 1.0 mol % (0.7 wt %) of TBD and excess amount of ethylene glycol (EG) at 190 C for 3.5 hours under atmospheric pressure to give bis(2-hydroxyethyl) tere...

Copoly(ethylene terephthalate-imide)s (PETIs) were synthesized by the melt copolycondensation of bis(2-hydroxyethyl)terephthalate with a new imide monomer, N,N9-bis[p-(2-hydroxyethoxycarbonyl)phenyl]-biphenyl-3,39,4,49-tetracarboxydiimide (BHEI). The copolymers were characterized by intrinsic viscosity, Fourier transform infrared, H NMR, differential scanning calorimetry, and thermogravimetric ...

Chemical recycling of Polyethylene terephthalate, PET, wastage has been investigated in this study. The aim of this work is recovery of terephthalic acid and ethylene glycols from PET waste. This process has been done in two stages. At the first stage, reaction between PET waste and sodium hydroxide for production of ethylene glycol and sodium terephthalate solution carried out in a stainless s...