This article describes the pyrolysis behavior of precipitated washed lignin in a Laminar Entrained Flow Reactor between 700 and 1000°C and at different residence times. Lignin was precipitated by acidification of softwood black liquor using CO2. After acid washing, the solid material was dried and sieved (80-100 μm). This material was then fed into the reactor at a rate of about 0.1 g/min. The ...

Pyrolysis is an environmental friendly alternative method compared with incineration, and the least time-consuming and smallest infrastructure footprint method compared with bio-chemical and thermo-chemical conversion. Baseline data for the pyrolysis of food waste was obtained in a kinetic study of the thermal decompositions by thermogravimetric analysis. To simulate the difference in the types...

Pyrolysis, one of the key thermochemical conversion technologies, is very promising to obtain char, oil and combustible gases from solid fuels. Kinetic modeling a crucial method for prediction rate analysis pyrolysis process. We recently developed new statistical model universal description fuel decomposition, which shows great potential in studying pyrolysis. This paper demonstrates three esse...

Biomass is of growing interest as a secondary energy source. Biomass could be converted to energy especially by pyrolysis or gasification. Understanding the mechanism and the kinetics of biomass pyrolysis and gasification could be the key to the design of industrial devices capable of processing vast amounts of biomass feedstock. There are multiple reactions describing the decomposition of biom...

The trend towards performance-based codes for achieving acceptable fire safety creates a significant demand for improved material properties and computer fire models. The performance-based engineering analysis is very difficult to achieve for wood-based materials because of their complex physical processes for pyrolysis and combustion. To address this need the cone calorimeter (ASTM E1354) was ...

Seeking a clean alternative energy resource is inevitable because of the limited fossil fuel energy resources and greenhouse gas emissions issue. Recently, advances in chemical and fuel processing technologies allow us to convert biomass to energy products with high energy density and value. Fast pyrolysis process is among the promising technologies for converting biomass to bio-oil and combust...

Kinetics-free equilibrium models can predict the exit gas composition, given the solid composition and the equilibrium temperature, but they cannot be used for reactor design Hence, there is a need to develop a combined transport and kinetic model which takes into account of the kinetics of homogeneous and heterogeneous chemical reactions, transport of volatiles produced, heat and mass transfer...