The nuclear quadrupole moment of In has been determined by combining the experimental nuclear quadrupole coupling constants and electric field gradients, calculated at the four-component CCSD~T! level of theory, of four indium halides. Our recommended value for the nuclear quadrupole moment of In is 770~8! millibarn. A basis set study at the Dirac–Hartree–Fock level shows a slow convergence of ...

This paper describes a study of controlling the coupling between the horizontal and the vertical betatron oscillations in the APS storage ring. Firit, we investigate the strengthening of coupling using two families of skew quadrupoles. Using smooth approximation, we obtained the formulae to estimate the coupling ratio defined as the ratio of the vertical and horizontal emittances or, for a sing...

This paper describes a study of controlling the coupling between the horizontal and the vertical betatron oscillations in the APS storage ring. First, we investigate the strengthening of coupling using two families of skew quadrupoles. Using smooth approximation, we obtained the formulae to estimate the coupling ratio defined as the ratio of the vertical and horizontal emittances or, for a sing...

We studied the electric quadrupole interactions of Oxygen isotopes in a T i 0 2 single crystal. For l 3 0 and 1 9 0 nuclei, quadrupole coupling constants were measured by the /3-NMR technique, and for the 1 7 0 nucleus the FT-NMR technique was utilized. We synthesized a T i0 2 single crystal which was enriched in 1 7 0 up to 5 atom % to observe NMR signals without any perturbations from impurit...

The electric quadrupole coupling constant of the 31Al ground state is measured to be νQ = ∣

It is shown that the "two-libron" lines in the Raman spectrum of solid hydrogen result from the large cubic anharmonicity of the quadrupole-quadrupole Hamiltonian. A localized picture is used to describe the interaction of two librational excitations on neighboring molecules, and dynamic interactions with other molecules are treated perturbatively. In this approximation the average single-libro...

The first investigation of the microwave spectrum of ethylenediamine (NH CH –CH NH ) showed that in the gas phase this molecule occurs in two conformers which both exhibit a large amplitude tunneling motion corresponding to an interchange of the roles of the amino groups. In conformer I, the tunneling splitting is about 172 MHz while it is only 2.7 MHz in conformer II. In the paper an analysis ...

Stabilizations and atomic level quadrupole coupling constant (CQ) properties have been investigated for graphene–like monolayers (G–monolayers) of boron nitride (BN), boron phosphide (BP), aluminum nitride (AlN), and aluminum phosphide (AlP) structures. To this aim, density functional theory (DFT) calculations have been performed to optimize the model structures and also to evaluate the CQ para...

density functional theory (dft) calculations have been performed to investigating the effects of themolecular oxygen impurity on the quadrupole coupling constant (qcc) parameters of armchair and zigzagboron nitride nanotubes (bnnts). optimization processes have been performed to relax the original andimpure structures of the investigated bnnts. afterwards, the qcc parameters have been evaluated...