A novel beta-cyclodextrin dimer, 1,10-phenanthroline-2,9-dimethyl-bridged-bis(6-monoammonio-beta-cyclodextrin) (phenBisCD, L), was synthesized. Its zinc complex (ZnL) has been prepared, characterized, and applied as a new catalyst for diester hydrolysis. The formation constant (logK(ML)=9.56+/-0.01) of the complex and deprotonation constant (pK(a)=8.18+/-0.04) of the coordinated water molecule ...

the present study was conducted to determine the relative contribution of initial quality and compositional parameters to the rate of changes (rctpc) in the content of total polar compounds (tpc), which is considered to be one of the most reliable indicators of heated oils quality, of olive oil during continuous heating at 180 ºc. the ratio between monounsaturated and polyunsaturated fatty acid...

The primary and secondary 18O isotope effects for the alkaline (KOH) and enzymatic (phosphotriesterase) hydrolysis of two phosphotriesters, O,O-diethyl p-nitrophenyl phosphate (I) and O,O-diethyl O-(4-carbamoylphenyl) phosphate (II), are consistent with an associative mechanism with significant changes in bond order to both the phosphoryl and phenolic leaving group oxygens in the transition sta...

A homogeneous preparation of cyclic CMP phosphodiesterase (Helfman, D. M., Shoji, M., and Kuo, J. F. (1981) J. Biol. Chem. 256, 6327-6334) was found to catalyze the hydrolysis of both pyrimidine and purine cyclic 2':3'- and 3':5'-nucleotides. Hydrolysis of cyclic 2':3'-nucleotides resulted in the formation of both 2'- and 3'-nucleotides, although relative amounts of the products were variable. ...

in order to evaluate the impact of different amounts of nitrogen fertilizer on growth and yield of two forage sorghum cultivars, a 2-year field experiment was carried out at the college of agriculture, shiraz university, shiraz, iran during 2010 and 2011 growing seasons. two factorial experiments were carried out in randomized block design with three replicates, in which the treatments included...

The pH-rate profiles for the hydrolysis of pyrophosphate (PP(V)) and pyrophosphite (PP(III), pyro-di-H-phosphonate) are a complex function of pH, reflecting the different ionic species and their relative reactivities. PP(III) is more reactive than PP(V) at all pHs and only PP(III) shows a hydroxide-ion reaction at high pH, so it is 10(10)-fold more reactive than PP(V) in 0.1 M NaOH. The pK(a2) ...

by-product of fisheries processing plants applicable protein. in this study effect of papain (plant origin), trypsin, pepsin (animal), alkalaz, prvtamks, flavrzaym (microbial), and temperatures of 30, 60, 90, 120, 150, and 180 minutes on the hydrolysis of rainbow trout waste were examined. the recovered peptone in the media as a source of bacteria lactobacillus plantarum and aeromonas hydrophil...