We use an atomic force microscope (AFM) to manipulate graphene films on a nanoscopic length scale. By means of local anodic oxidation with an AFM we are able to structure isolating trenches into single-layer and few-layer graphene flakes, opening the possibility of tabletop graphene based device fabrication. Trench sizes of less than 30 nm in width are attainable with this technique. Besides ox...

Single-layered graphene has unique electronic, chemical, and electromechanical properties. Recently, graphite exfoliation in N-methylpyrrolidone and molten salt has been demonstrated to generate monolayer exfoliated graphene sheets (EGS). However, these solvents are either high-priced or require special care and have high boiling points and viscosities, making it difficult to deposit the disper...

8 Abstract Graphene is a material with extraordinary properties. Its mechanical and electrical properties are unparalleled but the difficulties in its production are hindering its breakthrough in on applications. Graphene is a two-dimensional material made entirely of carbon atoms and it is only a single atom thick. In this work, properties of graphene and graphene based materials are described...

The extensive oxygen-group functionality of single-layer graphene oxide proffers useful anchor sites for chemical functionalization in the controlled formation of graphene architecture and composites. However, the physicochemical environment of graphene oxide and its single-atom thickness facilitate its ability to undergo conformational changes due to responses to its environment, whether pH, s...

Graphite intercalation compounds are formed by inserting guest molecules or ions between sp(2)-bonded carbon layers. These compounds are interesting as synthetic metals and as precursors to graphene. For many decades it has been thought that graphite intercalation must involve host-guest charge transfer, resulting in partial oxidation, reduction or covalent modification of the graphene sheets. ...

We use first-principles calculations to investigate the geometric, electronic and magnetic properties of metal adatoms on two typical graphene substrates (monolayer and bilayer). Firstly, we study the adsorption behaviors and the doping effects of metal atoms on pristine and defective bilayer graphene sheets (PBG and DBG). It is found that the metal doping in DBG sheets is more stable than that...

In this paper, the effect of the temperature change on the vibration frequency of mono-layer graphene sheet embedded in an elastic medium is studied. Using the nonlocal elasticity theory, the governing equations are derived for single-layered graphene sheets. Using Levy and Navier solutions, analytical frequency equations for single-layered graphene sheets are obtained. Using Levy solution, the...

this paper proposed analytical solutions for the buckling analysis of rectangular single-layered graphene sheets under in-plane loading on all edges simply is supported. the characteristic equations of the graphene sheets are derived and the analysis formula is based on the nonlocal mindlin plate. this theory is considering both the small length scale effects and transverse shear deformation ef...

Graphene based sheets have stimulated great interest due to their superior mechanical, electrical, and thermal properties. A general visualization method that allows quick observation of these single atomic layers would be highly desirable as it can greatly facilitate sample evaluation and manipulation, and provide immediate feedback to improve synthesis and processing strategies. Here we repor...