A high-performance liquid chromatography with ultraviolet detection (HPLC/UV) methodwhich was used solid-phase extraction for cleanup, was developed for the determination ofAzinphos methyl ,Phosalone, Diazinon and Chlorpyrifos residues in fruits. A full factorialexperimental design was used for development of HPLC condition and evaluation of effect ofthree factors (pH of mobile phase, percent o...

INTRODUCTION Since McCormick [1] introduced a method for deoxyribonucleic acid (DNA) extraction, known as solid-phase extraction (SPE), SPE using silica material [2] has become an essential technology for integrated point-of-care (POC) microsystem [3]. Recently, Price et al. provided an overview of these techniques [4], however it is still not easy to find the optimal solution for the microflui...

An isocratic high-performance liquid chromatographic method for the determination of testosterone (T) and epitestosterone (ET) in human urine using liquid-liquid or solid-phase extraction (SPE) is developed and validated. The optimum separation is achieved using a Hypersil C(18) column, water-acetonitrile (57:43, v/v) as the mobile phase and UV-absorbance detection at 245 nm. The recoveries obt...

Phosalone, malathion and diazinon were analyzed in corn oil using solid phase extraction (SPE)with lanthanum silicate as a new solid sorbent followed by gas chromatography with nitrogenphosphorus detection (GC-NPD). The efficiency of different eluents (methanol, dichloromethane,ethyl acetate, dichloromethane — ethyl acetate (1:1) and ethyl acetate — methanol (1:1)) werecompared for elution of o...

Solid phase extraction (SPE) is often used for enrichment and clean-up prior to analysis of dissolved organic matter (DOM) by electrospray ionization (ESI) coupled to ultrahigh resolution Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). It is generally accepted that extraction by SPE is not quantitative with respect to carbon concentration. However, little information is...

We report the formation of a highly stable amino stationary phase on diamond and demonstrate its use in solid-phase extraction (SPE). This process consists of spontaneous and self-limiting adsorption of polyallylamine (PAAm) from aqueous solution onto oxidized diamond. Thermal curing under reduced pressure or chemical cross-linking with a diepoxide was shown to fix the polymer to the particles....

solid phase extraction (spe) cartridge embedded with octadecyl c18 chain bounded to silica particles were used for the isolation and trace enrichment of pesticides from water samples collected from cotton, rice growing and municipal areas. the eluents were analyzed with high performance liquid chromatography (hplc) using methanol (100%) as mobiles phase at different uv-visible wavelengths. ddt ...

Abbreviations: AIBN, 2,20-azo-bis-isobutyronitrile; ASE, Accelerated solvent extraction; CAR, Carboxen; DAD, Diode-array detector; DI-SPME, Direct-immersion solid-phase extraction; DSPE, Dispersive solid-phase extraction; EGDMA, Ethylene glycol dimethacrylate; ESE, Enhanced solvent extraction; ESI, Electrospray ionization; FD, Fluorescence detection; FLD, Fluorimetric detection; GC, Gas chromat...

Due to high complexity of most food matrices and the low concentration (ppb levels) of HAs, sensitive and selective analytical methodology is needed. Solid-phase extraction (SPE) is generally used. However it involve tedious and time-consuming and have intrinsic disadvantages like the use of toxic solvents and plugging of the cartridges. These drawbacks can be avoided by using solid-phase micro...

In vitro bioassays are increasingly used for water quality monitoring. Surface water samples often need to be enriched to observe an effect and solid-phase extraction (SPE) is commonly applied for this purpose. The applied methods are typically optimised for the recovery of target chemicals and not for effect recovery for bioassays. A review of the few studies that have evaluated SPE recovery f...