Previous aerosol studies utilizing solid-phase microextraction (SPME) predominantly focused on volatile and semivolatile compounds in the gaseous phase. Difficulties were associated with quantitative analysis of these compounds when they were associated with atmospheric particles. The present study combines SPME technology with that of carboxen packed needles (needle trap, NT) for analysis of g...

Solid-phase microextraction (SPME) is an organic solvent-free sample preparation tool suitable for direct adsorption of analytes from the headspace or the aqueous phase of a matrix followed by desorption into a gas chromatograph (GC) or high-performance liquid chromatograph (HPLC) for subsequent analysis. The SPME technique is designed to accommodate the use of fibers coated with different poly...

The diagnostic potential and health implications of volatile organic compounds (VOCs) present in human feces has begun to receive considerable attention. Headspace solid-phase microextraction (SPME) has greatly facilitated the isolation and analysis of VOCs from human feces. Pioneering human fecal VOC metabolomic investigations have utilized a single SPME fiber type for analyte extraction and a...

To verify a theoretical mass balance and multiple compartment partitioning model developed to predict freely dissolved concentrations (FDCs) of hydrophobic organic chemicals (HOCs) using negligible depletion-solid phase microextraction (nd-SPME), a series of sediment slurry experiments were performed using disposable poly(dimethyl)siloxane (PDMS) coated-SPME fibers and (14)C-radiolabeled HOC an...

Solid-phase microextraction (SPME) is a versatile new technique for collecting headspace volatiles prior to GC analysis. The commercial availability of uniform SPME fibers makes routine, practical quantitation of headspace concentrations possible, but straightforward information for relating GC peak areas from SPME analyses to headspace concentrations has not been available. The calibration fac...

Sample preparation is an essential step in analysis, greatly influencing the reliability and accuracy of resulted the time and cost of analysis. Solid-Phase Microextraction (SPME) is a very simple and efficient, solventless sample preparation method, invented by Pawliszyn in 1989. SPME has been widely used in different fields of analytical chemistry since its first applications to environmental...

Human exposures to volatile organic compounds (VOCs) are associated with a wide range of health problems. Due to these adverse effects of VOCs on the human health, determination of trace levels of VOCs is very important for accurate assessment of indoor and outdoor exposure. Solid phase microextraction (SPME), needle trap device (NTD) and hollow fiber- liquid phase microextraction (HF-LPME) are...

This work presents a comparative study of the analytical characteristics of two methods for the analysis of carbonyl compounds in wine, both based on the derivatization with O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine hydrochloride (PFBHA). In the first method derivatives are formed in the solid phase extraction (SPE) cartridge in which the analytes have been previously isolated, while in the ...

Introduction. Polybrominated diphenyl ethers (PBDEs) are undoubtedly the most important group of organohalogenated compounds that captures the attention of environmental scientists in recent years. PBDEs are widely used flame retardant additives in polymers and textiles and are present in nearly all of our daily appliances. There are growing evidences that these brominated flame retardants are ...

The sensitivity and precision of headspace solid-phase micro extraction (HS-SPME) at an analyte solution temperature (T (as)) of +35 degrees C and a fiber temperature (T (fiber)) of +5 degrees C were compared with those for HS-SPME at T (as) and T (fiber) of -20 degrees C for analysis of the volatile organic compounds benzene, 1,1,1-trichloroethane, trichloroethylene, toluene, o-xylene, ethylbe...