Ionomers are interesting due to their applications in coatings, adhesives, films and packaging materials. A study of the underlying mechanisms for fracture in ionomers is consequently of both practical as well as theoretical interest. In this study, we employ high speed imaging coupled with uniaxial extensional rheometry to delineate the mechanics leading to the brittle fracture of ionomer melt...

The migration of packaging material constituents into food is a product of the interaction between the food and packaging material. This phenomenon is of importance because some migrating substances may be toxicologically carcinogenic and endanger the consumer safety. Polystyrenes are used in many food-contact applications for the packaging of aqueous-based, fatty and dry foods. The correlation...

background: the measurement data regarding the influent and effluent of wastewater treatment plant (wwtp) provides a general overview, demonstrating an overall performance of wwtp. nevertheless, these data do not provide the suitable operational information for the optimization of individual units involved in a wwtp. a full-scale evolution of wwtp was carried out in this study via a reconciled ...

The use of ionic liquids as functional building blocks based on pyridinium, imidazolium and phosphonium cations to achieve materials combining a structuration at nanoscale with the dramatic mechanical properties of the resulting ionomers has been successfully demonstrated for the first time in a fluorinated matrix.

Novel ionomers based on polybenzimidazole block sulfonated poly(arylene ether sulfone) show excellent thermal properties. The ionic aggregation of sulfonic acid groups leads to well-developed phase separated morphology and thus high proton conductivity at wide humidity range, up to 65 mS cm(-1) at 90% relative humidity.

Optimization of industrial styrene reactor design for two objectives using the non-dominated sorting genetic algorithm (NSGA) is studied. Both adiabatic and steam-injected reactors are considered. The two objectives are maximization of styrene production and styrene selectivity. The study shows that styrene reactor design can be optimized easily and reliably for two objectives by NSGA. It provi...

A physiologically based pharmacokinetic model which describes the behavior of inhaled styrene in rats accurately predicts the behavior of inhaled styrene in humans. The model consists of a series of mass-balance differential equations which quantify the time course of styrene concentration within four tissue groups representing (1) highly perfused organs, (2) moderately perfused tissues such as...

This study compared the flexural strengths and bond strengths to dentin and enamel of two brands of silver-reinforced glass ionomers with their respective unfilled glass-ionomer cements for luting. The results led to the following conclusions. 1. No significant differences in bond strengths to tooth substrates were recorded between silver-reinforced and unfilled glass ionomers. 2. Although the ...

Glass ionomer cements have been used in pediatric restorative dentistry for 20 years. Their usefulness in pediatric restorative dentistry is preferential relative to other materials because of their fluoride release, chemical adhesion to tooth structure, and availability to use in a variety of clinical scenarios. This paper reviews the use of glass ionomer materials in pediatric restorative den...

Herein, we report the phase inversion of ionomer-stabilized emulsions to form high internal phase emulsions (HIPEs) induced by salt concentration and pH changes. The ionomers are sulfonated polystyrenes (SPSs) with different sulfonation degrees. The emulsion types were determined by conductivity measurements, confocal microscopy and optical microscopy, and the formation of HIPE organogels was v...