Distributed Complex Event Processing (DCEP) is a commonly used paradigm to detect and act on situational changes of many applications, including the Internet Things (IoT). DCEP achieves this using simple specification analytical tasks data streams called operators their distributed execution set infrastructure. The adaptivity dynamics IoT applications essential very challenging in face changing...

Artificial photosynthesis: A novel amphiphilic cobalt(II) polypyridyl complex (CoC12) and an ruthenium photosensitiser (RuC12) were immobilised on liposomes to perform photocatalytic H2 generation in the presence of ascorbate (Hasc?) tris-2-carboxyethylphosphine hydrochloride (TCEP) as sacrificial electron donors. In such conditions, CoC12 was found be photostable, while optimised turnover numb...

Abstract Introduction Percutaneous left atrial appendage closure (LAAC) in AF patients is not inferior to oral anticoagulation (OAC) terms of systemic embolism. LAA Closure usually contraindicated presence intracardiac thrombus, a condition far from uncommon. The feasibility and safety transcatheter cerebral embolic protection (TCEP) has been reported literature as successful off – label option...

Diphenyl disulfides carrying alkyltelluro groups in the o-, m-, and p-positions were prepared using ortho-lithiation and lithium halogen exchange reactions. The novel antioxidants showed only minimal inhibitory effect on the azo-initiated peroxidation of linoleic acid in chlorobenzene until reduced to the corresponding thiophenols by tris(2-carboxyethyl)phosphine (TCEP). The best in situ genera...

A new transformation based on the Staudinger reaction is described, and its application in the design of a novel switch element to control peptide folding is demonstrated. We found that the azide switch is activated rapidly in water to promote acyl transfer using tris(2-carboxyethyl)phosphine hydrochloride (TCEP) via the Staudinger reaction. Our findings expand the repertoire of uses of the Sta...

Abstract Temporal clustering of extreme precipitation (TCEP) at subseasonal time scales often results in major impacts on humans and ecosystems. Assessment mitigation the risk such events requires characterization their weather/climate drivers spatial dependence. Here, we introduce a regionalization method that identifies coherent regions which likelihood TCEP exhibits similar dependence to lar...

Concentrations of 6 organophosphate esters (OPEs) were determined in 60 indoor (ID) and outdoor (OD) dust samples collected from 20 homes Basrah, Iraq. From each home, two ID collected, one elevated surfaces (ESD) the floor (FD) living room; while OD front yard same house. Total Σ6OPEs concentrations ranged between 681 17900 ng/g with median 5950, 3590 1550 ESD, FD samples, respectively. Chlori...

The extraction of high-quality ribonucleic acid (RNA) from tissues and cells is a key step in many biological assays. Guanidinium thiocyanate-phenol-chloroform (AGPC) widely used efficient method to obtain pure RNA most cells. However, it not with some like sperm because they are resistant chaotropic lysis solutions containing guanidinium thiocyanate such as Buffer RLT+ Trizol. Here, we show th...

Multimeric presentation, a rather effective way of enhancing peptide immunogenicity, is best exemplified by MAP (multiple antigenic peptide) dendrimers consisting of a branched Lys core on which several copies of the peptide epitope are displayed. While accessible by solid-phase synthesis, MAPs can also be conveniently made in solution, e.g., by linking the epitope (N-acetylated and with a C-te...

The occurrence of eight phosphorus flame retardants (PFRs) was investigated in 53 composite food samples from 12 food categories, collected in 2015 for a Swedish food market basket study. 2-ethylhexyl diphenyl phosphate (EHDPHP), detected in most food categories, had the highest median concentrations (9 ng/g ww, pastries). It was followed by triphenyl phosphate (TPHP) (2.6 ng/g ww, fats/oils), ...