Volatilization of agricultural chemicals is one process whereby chemicals may enter into parts of the environment where they were not intended. Starch encapsulation of pesticides has been proposed as a way of modifying pesticide behavior in the soil environment. This study was conducted to assess how starch encapsulation and temperature affect volatilization of atrazine [6.chloro-N-ethyI-N’-(l-...

We report thermal, X-ray diffraction (XRD) and cytotoxicity studies of complexes of fluconazole (FCZ) with Cu (II), Fe(II), Cd(II), Co(II), Ni(II), and Mn(II). From XRD measurements, FCZ and its metal complexes were identified as polycrystalline. Marked differences in the X-ray patterns of drug and its metal complexes revealed that the complexes are indeed different compounds and not just the m...

The feasibility of gas chromatography-mass spectrometry for the speciation of traces of dialkyldiselenides in the presence of dialkylselenides and inorganic selenium species is described, and the procedure is applied to environmental samples. The analysis is based on the reaction of dialkyldiselenide species with 1-fluoro-2,4-dinitrobenzene after volatilization of selenium species as alkylselen...

The relationship of merA gene expression (specifying the enzyme mercuric reductase) to mercury volatilization in aquatic microbial communities was investigated with samples collected at a mercury-contaminated freshwater pond, Reality Lake, in Oak Ridge, Tenn. Levels of merA mRNA transcripts and the rate of inorganic mercury [Hg(II)] volatilization were related to the concentration of mercury in...

In this work at the first step calcium hydroxide nano-particles were synthesized via sono-chemical method at room temperature. At the second step aminated multi-walled carbon nano-tubes was prepared via chemical modification of surfaces of CNT. Finally modified-MWCNT and Ca(OH)2 were added to paraloid matrix by aid of ultrasonic irradiation. Paraloid-modified-MWCNT-Ca(OH)2...

Phytoremediation is potentially effective for managing excessive selenium (Se) in drainage sediment residing in the San Luis Drain in central California. This 2-year field study examined the feasibility of amending drainage sediment (containing 4.78microgSeg(-1)) with methionine and casein to enhance volatilization without or with vegetation of Sporobolus airoides. Results show that without org...

Estimation of pesticide volatilization from plants is difficult because of our poor understanding of foliar penetration by pesticides, which governs the amount of pesticide available for volatilization from the leaf surface. The description of foliar penetration is still incomplete because experimental measurements of this complex process are difficult. In this study, the dynamics of leaf penet...

Benzene-based compounds are used as an intermediate for the synthesis of pesticides and other chemicals. Methoxybenzene derivatives such as anisole (methoxybenzene) and veratrole (1,2-dimethoxybenzene) are widely used in perfumes, insect pheromones, pharmaceuticals [1] and synthesis of organic compounds [2]. 1,2,3-Trimethoxybenzene is an organic compound with excellent physical properties due t...

The rate of volatilization of dinoseb may depend on soil acidity, temperature, surface soil moisture, the method of application, and the type of formulation (Kaufman 1976). Cohen et al. (1984) reported a volatilization half-life of 26 d. The significance of volatilization has been evidenced by the killing of plants by dinoseb vapours (Davis et al. 1954). Photodegradation is a major fate process...

in this work at the first step calcium hydroxide nano-particles were synthesized via sono-chemical method at room temperature. at the second step aminated multi-walled carbon nano-tubes was prepared via chemical modification of surfaces of cnt. finally modified-mwcnt and ca(oh)2 were added to paraloid matrix by aid of ultrasonic irradiation. paraloid-modified-mwcnt-ca(oh)2 nanocomposite was use...