In the present stady, thermochemical treatment in H2/NH3 atmosphere was used as a post-treatment for electroless Ni-P coatings on the AISI 4140 steel substrates. High phosphorus (9%) coatings with thicknesses of 2, 24 and 48 m were applied and the effects of the thermochemical treatment on the morphology, structural changes, roughness, hardness &#10&#10and wear resistance of coatings were studi...

Organophosphorous compounds are involved in many toxic compounds such as fungicides, pesticides, or chemical warfare nerve agents. The understanding of the decomposition chemistry of these compounds in the environment is largely limited by the scarcity of thermochemical data. Because of the high toxicity of many of these molecules, experimental determination of their thermochemical properties i...

Solar-driven thermochemical water splitting using non-stoichiometric oxides has emerged as an attractive technology for solar fuel production. The most widely considered oxide for this purpose is ceria, but the extreme temperatures required to achieve suitable levels of reduction introduce challenges in reactor design and operation, leading to efficiency penalties. Here, we provide a quantitati...

In this paper, the evolution in thermochemical behaviours of hospital plastic wastes and changes in chemical composition and characteristics of pyrolysis liquid products have been investigated by using different fixed bed reactor scales. The main objective is to identify the critical technical parameters enabling thermochemical process adaptation in function of raw materials chemical structure,...

This article reviews the progress, challenges and opportunities in numerical modelling of thermal transport, thermochemical reactions and thermomechanics in high-temperature solar thermochemical systems. Continuum-scale models are presented in mathematical detail while highlighting the literature that uses them. The discussion is enhanced by selected examples of numerical studies of solar therm...

The increase in the population of the planet and the rapid economic growth and, consequently, the high consumption of energy has created many environmental problems in the globe. Due to these reasons and the lack of renewability of these fossil fuels, there has been a steep trend towards the production of renewable fuels from natural sources, one of which is the production of energy from biomas...

the main objective of the present work was to synthesis polyamide 6 through anionic polymerization of ε-caprolactam in an internal mixer. the reaction time and the rheological properties of samples during the polymerization were studied. the samples were characterized by thermo gravimetry analysis (tga), differential scanning calorimeter (dsc) and ft-ir spectrometer. the melt flow behavior and ...

High-flux optical systems (HFOSs) are optical concentrators used to increase the radiative flux of the natural terrestrial solar irradiation. High radiative flux concentration leads to high energy density in solar receivers which allows to obtain high temperatures. In solar thermochemical applications, the hightemperature heat drives endothermic thermochemical reactions. HFOSs have been deploye...

Thermochemical conversion of biomass offers an efficient and economically process to provide gaseous, liquid and solid fuels and prepare chemicals derived from biomass. Computational fluid dynamic (CFD) modeling applications on biomass thermochemical processes help to optimize the design and operation of thermochemical reactors. Recent progression in numerical techniques and computing efficacy ...