Colloidal mesoporous silica (CMS) nanoparticles with a thin titania-enriched outer shell showing a spatially resolved functionality were synthesized by a delayed co-condensation approach. The titaniashell can serve as a selective nucleation site for the growth of nanocrystalline anatase clusters. These fully inorganic pure silica-core titania-enriched shell mesoporous nanoparticles show orthogo...

The interaction of chromium oxide with different titania-silica supports has been examined. The oxide supports investigated consisted of SiO,, TiO, , physical mixtures of TiO, and SiO,, a surface titania overlayer on SiO, (10% of theoretical monolayer) and a surface silica overlayer on TiO, (80% of theoretical monolayer). The supported chromium oxide catalysts were structurally characterized wi...

core-shell 12-tungstophosphoric acid/tio2 (hpw/tio2) nanoparticles at 10 and 20% of hpw have been synthesized by simple in-situ sol- gel method. characterization of the samples was carried out by x-ray diffraction (xrd), scanning electron microscopy (sem), fourier transform infrared (ftir). the x-ray diffraction patterns of as prepared solid samples, indicated characteristic peaks of titania wi...

Titania tubes with tunable wall thickness were produced by the sol-gel reaction of titanium(IV) n-butoxide in the presence of rod-shaped calcite particles that act as templates. A shell of amorphous titania was deposited around the calcite particles by sol-gel synthesis. The titania was crystallized to the anatase or rutile phase by sintering at different temperatures, and then acid etching was...

UNLABELLED BACKGROUND The work aims at improving photocatalytic activity of titania under Vis light irradiation using modification by Sn ions and an original, simple synthesis method. Tin-doped titania catalysts were prepared by thermal hydrolysis of aqueous solutions of titanium peroxo-complexes in the presence of SnCl4 or SnCl2 using an original, proprietary "one pot" synthesis not employi...

Experimental and theoretical studies on the compositional dependence of stability and compressibility in lithiated cubic titania are presented. The crystalline-to-amorphous phase transition pressure increases monotonically with Li concentration (from ∼17.5  GPa for delithiated to no phase transition for fully lithiated cubic titania up to 60 GPa). The associated enhancement in structural stabil...

Parameters and/or processes responsible for the stability of catalyst supports and ceramic membranes are discussed. Two major parameters/processes were identified which are responsible for the stabiliv of sol-gel derived nanostmctured oxides at elevated temperatures. They are metastable-to-stable phase transformation and structure and packing of primary particles within the aggregate. Based on ...

Nanoarchitectures of titania (TiO2) have been widely investigated for a number of medical applications including implants and drug delivery. Although titania is extensively used in the food, drug and cosmetic industries, biocompatibility of nanoscale titania is still under careful scrutiny due to the conflicting reports on its interaction with cellular matter. For an accurate insight, we perfor...

BACKGROUND Salicylic acid and its derivatives are widely used drugs with potential toxicity. The main areas of salicylate derivatives determination are biological liquids and pharmaceuticals analysis. RESULTS Silica-titania xerogel has been used for solid phase spectrophotometric determination of various salicylate derivatives (salicylate, salicylamide, methylsalicylate). The reaction conditi...