This photocatalytic conversion of carbon dioxide laboratory experiment is designed for an advanced undergraduate chemistry or chemical engineering majors laboratory course. It introduces the science of emerging sustainable energy technologies through hands-on experimentation. By photo-irradiating a glass flask containing water, catalyst, and carbon dioxide, students explore the potential of new...

The surface modification of titanium alloys is an effective method to improve their biocompatibility and tailor the material to the desired profile of implant functionality. In this work, technologically-advanced titanium alloys—Ti-15Mo, Ti-13Nb-13Zr and Ti-6Al-7Nb—were anodized in suspensions, followed by treatment in alkali solutions, with wollastonite deposition from the powder phase suspend...

Hybrid-layer degradation occurs because of acidic properties of currently used adhesive systems. Titanium tetrafluoride couples with tooth surface, and titanium compounds are not substituted. Caffeic acid phenethyl esther inhibits endogenous matrix metalloproteinases that cause hybrid-layer degradation. It was hypothesized that titanium tetrafluoride and caffeic acid phenethyl esther applicatio...

Complexation reactions of titanium tetraethoxide [Ti(OEt)4] and titanium tetra-n-butoxide [Ti(OBu )4] with 3-pentenoic acid (PA) and allylacetoacetate (AAA), in a 1 : 1M ratio, were studied in ethanol solution at room temperature. C-NMR and FTIR spectra showed that all PA and AAA completely reacted with both titanium alkoxides. Hydridosilane compounds such as triethoxysilane and triethylsilane ...

Recently, titanium compounds with one-dimensional nanostructures, such as nanotubes and nanofibers, have recently attracted much attention. Among these 1-D compounds, nanotubes composed of titanium dioxide and titanate are now being studied actively. Titanium dioxide nanotubes can be synthesized using porous anodic alumina membranes (Imai et al., 1999; Yamanaka et al., 2004), organic molecules ...

Titanium salts are widely used in pharmacy and industry as intensely white permanent pigment with good covering power in paints , paper , toothpaste , plastics and food dye s. This ion is a redox-active transition metal and may cause oxidative damages to lipids, proteins and DNA molecules. In spite of abundant literature, questions about the side effects of titanium ions...

This review collects the major progress in field of enantioselective transformations all types promoted by chiral titanium catalysts, covering literature since beginning 2015, illustrating power these green catalysts to provide many reactions. • Enantioselective titanium-catalyzed 1,2-additions carbon nucleophiles carbonyl compounds. Asymmetric sulfoxidations catalysts. Titanium epoxidations. r...