BORON INDUCED SURFACE MODIFICATION OF TRANSITION METALS by Raghasudha Vangaveti Boronizing is a thermo-chemical surface treatment of metals in which boron atoms diffuse into the metal substrate and form hard metallic borides. As a result of boronizing, several properties such as hardness, wear resistance, corrosion resistance, and high temperature oxidation resistance improve which make the met...

It was recently reported that polyanion/DNA/polycation ternary polyplexes markedly improve gene transfection activity in comparison with the original DNA/polycation binary polyplexes. In this study to explore the influence of the polyanion on the physico-chemical properties and biological activity of polyanion/pDNA/polycation ternary polyplexes four types of biocompatible polyanions were select...

Oxygen plays a critical role in strongly correlated transition metal oxides as crystal field effect is one of the key factors that determine the degree of localization of the valence d/f states. Based on the localization, a set of conventional mechanisms such as Mott-Hubbard, Charge-transfer and Slater were formulated to explain the antiferromagnetic and insulating (AFI) phenomena in many of th...

Strain and coordination effects in the adsorption on early transition metals were studied using density functional theory. We show that, in contrast to late transition metals, early transition metal surfaces with a less than half-filled local d-band exhibit lower adsorption energies upon lattice expansion and on low-coordinated sites, in agreement with predictions based on the d-band model. Thi...

A new functional low molecular-weight gelator (LMWG) based on crown-appended quaterthiophene was synthesized and investigated as a new alkali metal cation responsive material with enhanced fluorescence emission upon gel-to-sol phase transition.

OBJECTIVES: High levels of transition metals such as iron, nickel, chromium, copper, and lead are closely related to free radical generation, lipid peroxidation, formation of DNA strand breaks, and tumor growth in cellular systems. In order to determine the correlation to malignant growth in humans, we investigated the accumulation of heavy metals in 20 breast cancer biopsies and compared the f...