3D microstructure-performance relationships in Ni-YSZ anodes for electrolyte-supported cells are investigated in terms of the correlation between the triple phase boundary (TPB) length and polarization resistance (Rpol). Three different Ni-YSZ anodes of varying microstructure are subjected to eight reduction-oxidation (redox) cycles at 950 °C. In general the TPB lengths correlate with anode per...

Designing optimal microstructures for solid oxide fuel cell (SOFC) electrodes is complicated due to the multitude of electro-chemo-physical phenomena taking place simultaneously that directly affect working conditions of a SOFC electrode and its performance. In this study, a new design paradigm is presented to obtain a balance between electrochemical sites in the form of triple phase boundary (...

in the present study, the effect of porosity on the cathode microstructure (50:50 wt. % lsm: ysz) of a solid oxide fuel cell (sofc) has been examined. a 3-d finite element method for mixed ionic and electronic conducting cathodes (miec) is presented to study the effects of porosity on cell performance. each microstructure was realized using the monte carlo approach with the isotropic type of gr...

A traditional composite cathode for proton-conducting solid oxide fuel cells (H-SOFCs) is typically obtained by mixing materials and proton conducting electrolyte of BaCe0.7Y0.2Zr0.1O3–? (BZCY), providing chemical thermal compatibility with the electrolyte. Here, a series triple-conducing cobalt-free iron-based perovskites as cathodes H-SOFCs reported. Specifically, BaCexFe1–xO3–? (x = 0.36, 0....

Grain boundary engineered (GBE) materials have improved properties that are associated with the high fraction special Σ3 n boundaries in the microstructure, where n = 1, 2, or 3. Previous experimental studies with high purity nickel before and after GBE thermomechanical processing have shown that the fraction of Σ3 boundaries increased by at least factor of two [1]. Electron backscatter diffrac...

ticl4, ammonia, inorganic salts as raw material, nanometer composite-crystal tio2 powders were synthesized by two-step chemical method. precursors were crystallized with different phase and stable composite-crystal tio2 with anatase and rutile phase was prepared at low temperature. quantitative control of crystal phase was realized. remarkable factors including reaction ph value, reaction time,...

We report exceptional ductile behavior in individual double-walled and triple-walled carbon nanotubes at temperatures above 2000 degrees C, with tensile elongation of 190% and diameter reduction of 90%, during in situ tensile-loading experiments conducted inside a high-resolution transmission electron microscope. Concurrent atomic-scale microstructure observations reveal that the superelongatio...

Microstructure controls the properties of most useful materials. Thus an ability to control microstructure through the processing of materials is a key to optimization of materials performance. Most materials are polycrystalline and their grain structure is a very important aspect of their microstructure. Thanks to their complexity there is a great variety of grain boundary types even in relati...

The microstructure and softening behaviour have been investigated in an aluminum plate heavily deformed by equal channel angular extrusion and subsequently annealed at 170 °C. It is found that at this temperature the microstructure evolves by coarsening with no apparent signs of recrystallization even after 2 h of annealing. Both coarsening and softening are rapid within first 10 minutes of ann...