There is interest in using zirconia for biomedical applications as ball heads for total hip prostheses. Two potential types are under discussion: partially stabilized zirconia (PSZ) and tetragonal zirconia polycrystals (TZP) materials. Because of its enhanced material properties, TZP stabilized with yttria is favourable. To eliminate high amounts of natural radioactive impurities, the precursor...

To clarify controversial structures and phase stability in the Li-B system, we predicted energetically favorable compounds and crystal structures of the Li-B binary system at ambient pressure, mainly including Li6B5, LiB2, and LiB3, from ab initio evolutionary structure simulations and further investigated physical properties of stable Li-B compounds using first-principles methods. Metallic Li6...

Mn K-edge X-ray absorption spectroscopy (XAS) was used to gain insights into the geometric and electronic structures of [Mn(II)(Cl)2(Me2EBC)], [Mn(IV)(OH)2(Me2EBC)](2+), and [Mn(IV)(O)(OH)(Me2EBC)](+), which are all supported by the tetradentate, macrocyclic Me2EBC ligand (Me2EBC = 4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane). Analysis of extended X-ray absorption fine structure (EX...

Thermal Barrier Coatings are subjected to spallation and destabilization due to hot corrosion.Recently, Ceria Stabilized Zirconia (CSZ)-based TBCs have been intensively investigated for the YSZreplacement because CSZ has a much lower thermal conductivity and a higher expected thermalexpansion coefficient than those of YSZ. In this research, Yttria stabilized zirconia (YSZ) andceria stabilized z...

BACKGROUND The potential transfer of engineered nanoparticles (ENPs) from plants into the food chain has raised widespread concerns. In order to investigate the effects of ENPs on plants, young cabbage plants (Brassica oleracea) were exposed to a hydroponic system containing yttrium oxide (yttria) ENPs. The objective of this study was to reveal the impacts of NPs on plants by using K-edge subtr...

Objectives: To test the wear of enamel against Yttria Tetragonal Zirconia Polycrystals (Y-TZP) in comparison to the wear of enamel against a noble white high Palladium alloy. Methods: A total of 20 specimens were used, 10 of Y-TZP and 10 of High Palladium alloy, both were subjected to 202,800 contacts against an enamel rod 2x2 mm in cross section under a mean load of 475.04g leading to a mean f...

Densification and grain growth mechanisms of Yttria-Stabilized Zirconia sintered by Spark Plasma Sintering are investigated. trajectories four commercial submicronic powders with different average particle sizes yttria amounts have been established sintering regimes determined. determined in the regime where densification is occurring without using a model derived from hot-pressing. Grain conve...

Well-aligned, densely distributed ZrO2 nanorod arrays were fabricated using a non-catalytic, templatefree metal–organic chemical vapour deposition process at a reaction temperature of 1000 C. The reaction temperature was found to play a key role in product morphology, with particle thin films obtained at 550 C and nanorod arrays produced at 1000 C. Increasing the reaction temperature led to the...

This paper presents to use the Resonant Ultrasound Spectroscopy (RUS) as nondestructive examination method for determination of the density changing, elastic and geometrical properties of the object to be examined. The method is applied at the noninvasive evaluation of the femoral head prosthetic and of the artificial cervical discs made from yttria stabilized tetragonal zirconia. This method d...

There is a continuous search for an alternative oxide material to the yttria-stabilized zirconia (7YSZ), which currently serves as the thermal barrier coating materials for turbine engines [1]. The new material should have low thermal conductivity, high temperature stability, and ferroelastic toughening as exhibited by the 7YSZ. Therefore in this study, the Y-Ta-Zr-O system was investigated. Th...