mg(oet)2 with spherical morphology is one of the most important precursors for the preparation of industrialziegler-natta catalysts. in the present article, morphology evolution of mg(oet)2 particles is studied in the courseof the synthesis. the morphology of mg(oet)2 particles is observed throughout the process by sem. the resultsshow that mg(oet)2 particles are formed through i) seed generati...

primary mgcl2.3.3etoh adduct (pct1) was prepared by melt quenching method and then submitted into a programmed thermal dealcoholation project using a fluidized bed reactor. during thermal dealcoholation program, different mgcl2.netoh support samples with n= 3.0, 2.7, 2.4, and 2.1 were selected and named as pct2 to pct5, respectively. structural analysis of the support samples showed a significa...

Understanding the kinetics of olefin polymerization with Ziegler-Natta and related catalysts means identifying the main kinetic parameters such as k(p) and concentration of active sites. The high-pressure quenched-flow technique could be an absolute method for counting active sites and for activation studies of molecular catalysts. A kinetic study of metallocene catalysts and a phenoxy-imine ti...

a new model based on a combination of the polymeric multigrain and multilayer models has been developed to predict the polymerization rate, particle growth, morphology, effective parameters on broadening of the molecular weight distribution, number and weight average of the molecular weight, isotacticity index and bulk density of polymer. mathematical correlations and the kinetics used in this ...