نتایج جستجو برای: پوسته aupd
تعداد نتایج: 5240 فیلتر نتایج به سال:
Abstract Furan‐2,5‐dimethylcarboxylate (FDMC), along with ethylene glycol (EG), is the key monomer to produce (poly‐(ethylene‐furanoate) (PEF). Noble metal‐based catalysts can convert hydroxymethyl furfural (HMF) FDMC in methanol through liquid phase catalytic oxidative esterification. In this work, performance of Au, Pd and AuPd NPs supported on nanosized nickel oxide (nNiO) have been evaluate...
In this work we address the challenge of furthering our understanding of the driving forces responsible for the metal-metal interactions in industrially relevant bimetallic nanocatalysts, by taking a comparative approach to the atomic scale characterization of two core-shell nanorod systems (AuPd and AuRh). Using aberration-corrected scanning transmission electron microscopy, we show the existe...
Glioblastoma multiforme (GBM) is an extremely malignant brain tumor. To identify new genomic alterations in GBM, genomic DNA of tumor tissue/explants from 55 individuals and 6 GBM cell lines were examined using single nucleotide polymorphism DNA microarray (SNP-Chip). Further gene expression analysis relied on an additional 56 GBM samples. SNP-Chip results were validated using several technique...
We report that the oxygen binding energy of alloy-core@Pt nanoparticles can be linearly tuned by varying the alloy-core composition. Using this tuning mechanism, we are able to predict optimal compositions for different alloy-core@Pt nanoparticles. Subsequent electrochemical measurements of ORR activities of AuPd@Pt dendrimer-encapsulated nanoparticles (DENs) are in a good agreement with the th...
Bimetallic AuPd supported on different carbonaceous materials and TiO2 was tested in the liquid phase oxidation of commercial grade and raw glycerol. The latter was directly obtained from the base-catalyzed transesterification of edible rapeseed oil using KOH. The best catalytic results were obtained using activated carbon and nitrogen-functionalized carbon nanofibers as supports. In fact, the ...
Utilizing surface enhanced Raman spectroscopy (SERS) to in situ monitor a catalytic reaction requires a bi-functional platform which is both catalytically and plasmonically active. In this study, we developed a novel bimetallic nanostructure, featuring Au-Pd alloy horns selectively grown on the end of Au nanorods (AuNR@AuPd), and employed electron tomography and electron energy loss spectroscop...
It is demonstrated that gas-phase CO pressure higher than approximately 0.1 Torr is required to segregate a sufficient amount of Pd to the surface of a well-annealed AuPd(100) sample to form contiguous Pd sites. These contiguous sites are critical in dissociating O(2) for low-temperature CO oxidation, where CO chemisorbed on Au sites clearly participates in the reaction at temperatures below ap...
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