We have studied the effect of dynamical correlations on the electronic structure of single Co adatoms on graphene monolayers with a recently developed method for nanoscopic materials that combines densityfunctional calculations with a fully dynamical treatment of the strongly interacting 3d electrons. The coupling of the Co 3d shell to the graphene substrate and hence the dynamic correlations a...

Recent advances in three-dimensional (3D) graphene assembly have shown how we can make solid porous materials that are lighter than air. It is plausible that these solid materials can be mechanically strong enough for applications under extreme conditions, such as being a substitute for helium in filling up an unpowered flight balloon. However, knowledge of the elastic modulus and strength of t...

We introduce a high-performance molecular sensor using self-corrugated chemically modified graphene as a three dimensional (3D) structure that indicates anisotropic charge distribution. This is capable of room-temperature operation, and, in particular, exhibiting high sensitivity and reversible fast response with equilibrium region. The morphology consists of periodic, "cratered" arrays that ca...

Graphene oxide hydrogel is used as a reactive template to prepare nanoporous materials with a 3D microstructure. The as-prepared porous MnO2 shows a capacitance retention of ~70.6% at a current density as high as 15 A g(-1), resulting from the 3D interconnected ion transport channel replicated from the graphene oxide hydrogel.

hydrothermal reduction (HR), [ 13–15 ] electrochemical reduction, [ 16–18 ] and chemical vapor deposition. [ 19,20 ] Among these approaches, the HR is considered as one of the most attractive techniques, because of its simplicity, low cost, and especially the green reduction without generating any contamination, due to the simultaneous process of self-assembly and reduction of graphene oxide (G...

Three dimensional (3D) plasmonic nanostructure is perfect for the surface-enhanced Raman scattering (SERS) and also very suitable for surface catalytic reaction, but how to design and fabricate is still a robust task. Here, we show a 3D plasmonic nanohybrid of vertical graphene-nanosheet sandwiched by Ag-nanoparticles on the silicon nanocone array substrate for enhanced surface catalytic reacti...

In the race of gaining higher energy density, carbon's capacity to retain power density is generally lost due to defect incorporation and resistance increment in carbon electrode. Herein, a relationship between charge carrier density/charge movement and supercapacitance performance is established. For this purpose we have incorporated the most defect-free pristine graphene into defective/sacrif...

Copyright © Korean Carbon Society http://carbonlett.org Abstract Porous materials play a vital role in science and technology. The ability to control their pore structures at the atomic, molecular, and nanometer scales enable interactions with atoms, ions and molecules to occur throughout the bulk of the material, for practical applications. Three-dimensional (3D) porous carbon-based materials ...

Graphene and other two-dimensional materials have unique physical and chemical properties of broad relevance. It has been suggested that the transformation of these atomically planar materials to three-dimensional (3D) geometries by bending, wrinkling, or folding could significantly alter their properties and lead to novel structures and devices with compact form factors, but strategies to enab...

Two-dimensional (2D) graphene emerged as an outstanding material for plasmonic and photonic applications due to its charge-density tunability, high electron mobility, optical transparency and mechanical flexibility. Recently, novel fabrication processes have realised a three-dimensional (3D) nanoporous configuration of high-quality monolayer graphene which provides a third dimension to this mat...