In this paper we develop an analytical framework for the study of electrochemical impedance of mixed ionic and electronic conductors (MIEC). The framework is based on non-equilibrium thermodynamics and it features the coupling of electrochemical reactions, surface transport and bulk transport processes. We utilize this work to analyze two-dimensional systems relevant for fuel cell science via t...

In this module we will learn the most important principles of making electrical measurements in general, i.e., to obtain voltages and currents using the appropriate instruments and connections, and to understand and minimize sources of error. Furthermore, we will discuss selected electrical measurement methods used to obtain chemical and physical information of liquids, solids, and interfaces. ...

Abstract In this report, we incorporate activated carbon (AC) onto aluminum substrate via doctor blade method to produce an all-solid-state supercapacitor. The electrochemical properties of the supercapacitor were characterized by cyclic voltammetry and impedance spectroscopy. Galvanostatic charge/discharge tests also carried out exhibit stability AC-based curves showed good capacitive behavior...

Electrostatic-force-sensitive scanning probe microscopy (SPM) is used to investigate grain boundary behavior in polycrystalline BiFeO3 ceramics. Scanning surface potential microscopy (SSPM) of a laterally biased sample exhibits potential drops due to resistive barriers at the grain boundaries. In this technique, the tips acts as a moving voltage probe detecting local variations of potential ass...

in this study, we explained a nanobiosensor for dna sequence detection, featuring sequence specificity, cost efficiency, speed, and ease of use. without the need for labels or indicators, it may be ideal for the detection of biological agents. this review describes recent advances in electrochemical impedance spectroscopy (eis) with an emphasis on using nanoparticles and nanotechnology. a power...

Cathodic and anodic overpotentials were measured using current interruption and AC impedance spectroscopy for two separate solid oxide fuel cells (SOFCs). The fuel cells used yttria-stabilized zirconia (YSZ) as the electrolyte, strontium-doped lanthanum manganite (LSM) as the cathode, and a porous YSZ layer impregnated with copper and ceria as the anode. The Cu/CeO2/YSZ anode is active for the ...

The structure and dynamics of the solutions of LiPF6 in propylene carbonate over a concentration range of 0-3 mol/kg are studied with neutron spin echo spectroscopy, alternating-current (AC) conductometry, and shear impedance spectroscopy. The neutron diffraction shows a prepeak at ≈10 nm(-1) in addition to the main peak at ≈14 nm(-1) when the concentration of the salt is no less than 2 mol/kg....