The reaction of aqueous solutions of amino-guanidine hydrogennitrate and acetyl-acetone produces the title pyrazole salt, C(7)H(18)N(8) (2+)·2NO(3) (-). The crystal structure is stabilized by a complex N-H⋯O hydrogen-bonding network. The difference in the engagement of the two nitrate anions in hydrogen bonding is reflected in the variation of the corresponding N-O bond lengths.

Continuing chemical investigation on the acetone extracts of the soft coral Sarcophyton ehrenbergi collected off the coast of San-hsian-tai, Taitong County, Taiwan led to the isolation of two new diterpenoids, ehrenbergol C and acetyl ehrenberoxide B (1 and 2). The structures of these isolated metabolites were elucidated through extensive spectroscopic analyses. Moreover, in vitro tests show th...

[1] The photodissociation of acetone has been studied over the wavelength (l) range 279–327.5 nm as a function of temperature (T) and pressure (p) using a spectroscopic method to monitor the acetyl (CH3CO) radical fragment. Above 310 nm the quantum yield (QY) is substantially smaller than previous measurements, and decreases with T. The QYs for production of CH3CO + CH3 and CH3 + CH3 + CO have ...

The development of tools for genetic manipulation of Clostridium ljungdahlii has increased its attractiveness as a chassis for autotrophic production of organic commodities and biofuels from syngas and microbial electrosynthesis and established it as a model organism for the study of the basic physiology of acetogenesis. In an attempt to expand the genetic toolbox for C. ljungdahlii, the possib...

This paper reports an experimental study on the synthesis and electrochemical properties of InVO4 nanotube arrays fabricated by capillary-enforced sol-filling in templates in combination with solvent-evaporation induced deposition. InVO4 sol was synthesized using the sol–gel route from vanadium oxoisopropoxide and indium nitrate with ethanol as the solvent. Nanotube arrays of InVO4 were prepare...

In this contribution, new derivatives of bicyclic fused rings with bridgehead nitrogen 3-substituted imidazo/pyrimidine A1-A3 were synthesized by reacting 2-aminobenzothiazol, acetyl acetone, and different substituted aldehydes in a one-pot reaction. These compounds then condensed 4-bromobenzaldehyde 4-(N,N-dimethylamino)benzaldehyde to form chalcone A4-A9. Ring closure these A4-A9 urea malonon...

1. The methods for the assay of choline acetyltransferase were based on the reaction between labelled acetyl-CoA and unlabelled choline to give labelled acetylcholine. 2. Both synthetic acetyl-CoA and acetyl-CoA formed from sodium [1-(14)C]acetate or sodium [(3)H]acetate by incubation with CoA, ATP, Mg(2+) and extract from acetone-dried pigeon liver were used. 3. [1-(14)C]Acetylcholine was isol...