This paper first deals with the screening and optimization of Fe(III)-based adsorbents for arsenic adsorption from 0.2 to 16 ppm test solutions of arsenite/arsenate. The best adsorption capacity has been reported on alpha-FeO(OH) on an adsorbent weight basis. Better results were found on intercalated Fe-montmorillonites for arsenite adsorption below the equilibrium dissolved As concentration of...

the adsorption study was conducted on three japanese soils with different soil properties to characterize the adsorption pattern of arsenic (as). double tube method was used to find out the effect of soil moisture levels on as adsorption. for this study, besides double tube method, conventional batch method also was used. the as adsorption showed two phase kinetics. an initial and rapid adsorpt...

Widespread arsenic contamination of mining wastewater of Zarshouran (West Azerbaijan province) has led to a massive epidemic of arsenic poisoning in the whole of surrounding areas. It is estimated that approximately all agriculture fields are being irrigated with the water that its arsenic concentrations elevated above the World Health Organization’s standard of 10 parts per billion. A novel ad...

The geochemical fates of iron and arsenic are so closely correlated that methods of arsenic removal from water are in general based on the high adsorptive affinity of this metalloid with iron (hydr)oxides. Under anoxic conditions, however, reductive dissolution of iron (hydr)oxides can take place, and arsenic may be released into the surrounding environment. The purpose of this study was to inv...

*Correspondence: Emilia Morallón, Departamento de Química Física e Instituto Universitario de Materiales, University of Alicante, P.O. Box 99, San Vicente del Raspeig E-03080, Spain e-mail: [email protected] The adsorption and electroadsorption of arsenic from a natural water has been studied in a filter-press electrochemical cell using a commercial granular activated carbon as adsorbent and Pt/Ti...

As a type of emerging nanomaterial, hydroxylated multiwalled carbon nanotubes (OH-MWCNTs) may interact with other pollutants in the aquatic environments and further influence their toxicity, transport, and fate. Thus, evaluation of toxicity to arsenic in the presence of CNTs needs to receive much more attention. The present study was conducted to explore the underlying mechanisms of OH-MWCNT-in...

The interactions of arsenic species with platinum and porous carbon electrodes were investigated with an electrochemical quartz crystal microbalance (EQCM) and cyclic voltammetry in alkaline solutions. It is shown that the redox reactions in arsenic-containing solutions, due to arsenic reduction/deposition, oxidation/desorption, and electrocatalyzed oxidation by Pt can be readily distinguished ...

Two common waste materials, red mud and fly ash, were used to produce a new nano-hybrid adsorbent by heat treatment with alkali addition. The new zeolitic structure formation of the hybrid adsorbent was revealed using the BET surface area, XRD, and SEM analyses. This hybrid adsorbent was utilized to remove arsenic from synthetic and real waste waters by batch and column adsorption experiments. ...

The chemical speciation of arsenic in sediments and porewaters of aquifers is the critical factor that determines whether dissolved arsenic accumulates to potentially toxic levels. Sequestration of arsenic in solid phases, which may occur by adsorption or precipitation processes, controls dissolved concentrations. We present synchrotron x-ray absorption spectra of arsenic in shallow aquifer sed...

The effects of various geochemical processes on arsenic enrichment in a high-arsenic aquifer at Jianghan Plain in Central China were investigated using multivariate models developed from combined adaptive neuro-fuzzy inference system (ANFIS) and multiple linear regression (MLR). The results indicated that the optimum variable group for the AFNIS model consisted of bicarbonate, ammonium, phospho...