An intercomparison exercise was conducted for the quantification of arsenic species in spiked human urine. The primary objective of the exercise was to determine the variance among laboratories in the analysis of arsenic species such as inorganic As (As+3 and As+5), monomethylarsonic acid (MMA), and dimethylarsinic acid (DMA). Laboratories that participated had previous experience with arsenic ...

BACKGROUND Determination of arsenic species in saliva is potentially useful for biomonitoring of human exposure and studying arsenic metabolism. Arsenic speciation in saliva has not been reported previously. METHODS We separated arsenic species in saliva using liquid chromatography (LC) and quantified them by inductively coupled plasma mass spectrometry. We further confirmed the identities of...

This study was conducted to investigate the effect of external iron status and arsenic species on chelant-enhanced iron bioavailability and arsenic uptake. Rice seedlings (Oryza sativa L.) were used as model plant, and were grown in artificially contaminated sandy soils irrigated with Murashige and Skoog (MS) culture solution. Arsenate uptake in roots and shoots of rice seedlings were affected ...

In contrast to arsenic (As) poisoning caused by naturally occurring inorganic arsenic-contaminated water consumption, coal arsenic poisoning (CAP) induced by elevated arsenic exposure from coal combustion has rarely been reported. In this study, the concentrations and distributions of urinary arsenic metabolites in 57 volunteers (36 subjects with skin lesions and 21 subjects without skin lesion...

http://dx.doi.org/10.1016/j.jes.2015 1001-0742/© 2015 The Research C Arsenic is one of the most common inorganic contaminants in groundwater worldwide, mainly due to the release of naturally occurring arsenic from aquifer sediments (Amini et al., 2008; Li and Cai, 2015; Rahman et al., 2015). Naturally occurring arsenic exists predominantly in arsenate and arsenite species in groundwater. Arseni...

This study reports data on arsenic speciation in two green algae species (Cladophora sp. and Chara sp.) and in five aquatic plants (Azolla sp., Myriophyllum aquaticum, Phylloscirpus cf. desserticola, Potamogeton pectinatus, Ruppia filifolia and Zannichellia palustris) from the Loa River Basin in the Atacama Desert (northern Chile). Arsenic content was measured by Mass spectrometry coupled with ...

The influence of ethylenediaminetetraacetic acid (EDTA) and chemical species on arsenic accumulation in aquatic floating macrophyte Spirodela polyrhiza L. (duckweed) was investigated. The uptake of inorganic arsenic species (arsenate; As(V) and arsenite; As(III)) into the plant tissue and their adsorption on iron plaque of plant surfaces were significantly (p<0.05) higher than those of organic ...

The toxic effects of arsenicals are significantly modified by numerous biological and abiotic factors. The toxicity of arsenic in the environment is affected by temperature, pH, Eh, organic content, phosphate concentration, adsorption to solid matrices, the presence of other substances and toxicants, duration of exposure and the arsenic species present. In general, inorganic arsenicals are more...

background facultative marine fungi could potentially be arsenic tolerant and may be able to remove this highly poisonous metal from the environment. objectives the objective of this work was to explore the degree of tolerance and removal efficiency of two facultative marine fungi. materials and methods facultative marine fungi aspergillus flavus and rhizopus spp. were exposed to 25 mg/l and 50...

The coordination environment and the redox speciation of arsenic in a newly discovered arsenic hyper-accumulating fern (Pteris vittata L) were investigated by X-ray absorption spectroscopy. This method allowed us to probe arsenic directly, i.e., with minimal sample preparation. The results indicate that arsenic is predominantly accumulated as As(III) in the leaves. XANES and EXAFS results show ...