A [P44414][Cl]-NaCl-H2O ionic liquid-based aqueous biphasic system shows promising results for the separation of cobalt(II) and nickel(II) by homogeneous liquid-liquid extraction. The extracting phase consists of a hydrophilic ionic liquid that is salted-out by sodium chloride, indicating that there is no need for using hydrophobic ionic liquids.

the anticoagulant racemic warfarin is synthesized by the michael addition of 4-hydroxycoumarin with benzalacetone in the present of equimolar amounts of imidazolium based ionic liquids [bmim] bf4 and [bmim] br and other reaction solvents such as h2o, pyridine and ammonia in five different tests. also synthesis of a derivative of warfarin (2-methyl-4-phenyl pyrano [3, 2-c] chromen-5(4h)-one) und...

The lack of suitable nonflammable electrolytes has delayed battery application in electric vehicles. A new approach to improve the safety performance for lithium battery is proposed here. This technology is based on a nanogelator-based solid electrolyte made of porous oxides and an ionic liquid. The electrolyte is fabricated using an in situ method and the porous oxides serve as a nonflammable ...

in this paper, aggregation behaviors of aqueous solutions of short chain hydrophilic ionic liquids (ils), 1 – allyl - 3 - methylimidazolium chloride ([amim]cl), 1 - ethyl - 3 - methylimidazolium chloride ([emim]cl), 1 - butyl - 3 - methylimidazolium chloride ([bmim]cl), 1 - butyl - 3 - methylimidazolium tetrafluoroborate ([bmim]bf4) were investigated using conductivity and laser light scatterin...

in recent years there has been a great deal of attention paid by researchers in investigating ionic liquids (ils) mainly due to the tremendous potential that ionic liquids have in reaction and separation technology. sonic speed is an important thermodynamic property of ionic liquids (ils) and always chosen as a source to determine other properties. a database for the sonic speed of pure ils cre...

the ionic liquid li(ohch2ch2nh2)(cf3oac) was found to efficiently catalyze the three-component reaction between different enols, aldehydes, and malononitrile , leading to rapid synthesis of 2-amino-4h-chromene derivatives in fairly high yields. the catalyst is easily prepared, highly stable, simple to handle and recycled for several times without significant loss of activity. the method is simp...

a carbon nanocomposite electrode has been designed by incorporation of montmorillonite nanoclayinto the carbon ionic liquid electrode for the electrochemical determination of amitriptiline . the surface ofthe proposed electrode was characterized by scanning electron microscopy. the presence of ionic liquid asa binder is believed to be responsible for the electrocatalytic activity of the propose...

an efficient protocol for the selective oxidation of primary alcohols to aldehydes withh5io6/v2o5 in ionic liquid [bmpy][pf6] has been developed. high yields of the products, mildreaction conditions and simple experimental procedure make this protocol complementary tothe existing methods. the catalyst can be reused for several times without obvious loss of thecatalytic activity.

the density (d), speed of sound (u) and electrolytic conductivity (λ) for systems containing acetaminophen, ionic liquid {1-octyl-3-methyl imidazolium bromide, [omim] br} and water have been measured at t = 293.15-308.15 k. the measured data have been applied to calculate, standard partial molar volume ( ), hepler’s constant , apparent molar isentropic compressibility (kφ), transfer volume ( ),...

The present study aims at evaluating the capability of phosphate-based salts, whose anions can coexist in water depending on the media pH, to promote aqueous biphasic systems (ABS) formation with 1-butyl-3methylimidazolium-based ionic liquids, as well as to infer on the influence of the ionic liquid anion in the overall process of liquid–liquid demixing. In this context, novel phase diagrams of...