a kernel $j$ of a digraph $d$ is an independent set of vertices of $d$ such that for every vertex $w,in,v(d),setminus,j$ there exists an arc from $w$ to a vertex in $j.$in this paper, among other results, a characterization of $2$-regular circulant digraph having a kernel is obtained. this characterization is a partial solution to the following problem: characterize circulant digraphs which hav...

Study the relationship between unitary matrices and their patterns is motivated by works in quantum chaology (see, e.g., [KS99]) and quantum computation (see, e.g., [M96] and [AKV01]). We prove that if a Cayley digraph is a line digraph then it is the pattern of a unitary matrix. We prove that for any finite group with two generators there exists a set of generators such that the Cayley digraph...

Let D be a digraph, V (D) and A(D) will denote the sets of vertices and arcs of D, respectively. A digraph D is 3-transitive if the existence of the directed path (u, v, w, x) of length 3 in D implies the existence of the arc (u, x) ∈ A(D). In this article strong 3-transitive digraphs are characterized and the structure of non-strong 3-transitive digraphs is described. The results are used, e.g...

Given a matrix M of size n, the digraph D on n vertices is said to be the digraph of M , when Mij 6= 0 if and only if (vi, vj) is an arc of D. We give a necessary condition, called strong quadrangularity, for a digraph to be the digraph of a unitary matrix. With the use of such a condition, we show that a line digraph, − → L D, is the digraph of a unitary matrix if and only if D is Eulerian. It...

Let D be a digraph, V (D) and A(D) will denote the sets of vertices and arcs of D, respectively. A (k, l)-kernel N of D is a k-independent (if u, v ∈ N then d(u, v), d(v, u) ≥ k) and l-absorbent (if u ∈ V (D) − N then there exists v ∈ N such that d(u, v) ≤ l) set of vertices. A k-kernel is a (k, k − 1)-kernel. A digraph D is transitive if (u, v), (v, w) ∈ A(D) implies that (u,w) ∈ A(D). This co...

Abstract This thesis is concerned with the synthesis of -sultams and the development of new routes for the synthesis of bicyclic versions of these molecules as potential anti-bacterials. The synthesis of 1-azetines, 1,2-thiazetin-1,1-dioxides and isothiazol-1,1-dioxides as precursors of bicyclic heterocycles is described. 1-Azetines were synthesised from azetidin-2-ones prepared via the [2+2] c...

We developed a 1,3-dipolar cycloaddition reaction of azomethine imines with terminal alkynes catalyzed by group 11 metal amides to provide N,N-bicyclic pyrazolidinone derivatives. This reaction afforded the cycloadducts in a unique 5,7-disubstituted manner. Furthermore, we succeeded in applying this catalysis to asymmetric reactions, and the desired heterocycles were produced in high yields wit...