The effective use of pencil as a matrix for matrix-assisted laser desorption/ionisation (MALDI) for the study of actinides has previously been demonstrated (Black et al., Rapid Commun. Mass Spectrom. 2006; 20: 1053). Here, the scope of the types of molecules amenable to analysis by this method has been extended, establishing that approximately 90% of a library containing 50 diverse small molecu...

Agglomerative hierarchical cluster analysis was used to group similar spectra from a large database of samples. Based on angles between reflectance vectors of members of a cluster, a reflectance vector was selected as representative of that cluster. Representative samples were grouped together and stored as new calibration targets. Simulated wide-band imaging with glass filters was performed us...

A collinear backscattering Mueller matrix (CBMM) imaging system has clear advantages in the detection of bulk biological tissues, which are highly scattering and depolarizing. Due to double-pass configuration noise system, calibration a is usually complex poor accuracy. In this work, we propose an alternative modified eigenvalue method (ECM) based on equivalent standard sample. For better suppr...

Adaptive beamforming methods degrade in the presence of model mismatch. In this paper, we develop a modified interference covariance matrix reconstruction based beamformer that is robust against large array calibration errors. The calibration errors can come from the element position errors, and/or amplitude and phase errors, etc.. The proposed method is based on the fact that the sample covari...

In this work we focus on the swaptions “second-order automatic cascade calibration” methodology for the Libor Market Model (LMM), first appeared in Brigo and Mercurio (2001). Such analytical calibration induces a direct correspondence between swaption market volatilities and LMM volatility parameters. We present the basic algorithm and a possible extension, pointing out its main features and so...

In order to deal with the matrix effect in the simultaneous determination of multi-components in a complex system, we have developed a novel method named matrix coefficient multivariate calibration method (MCMCM) for simultaneously determining n analytes in complex systems. The calibration models of n analytes, which are based on the experimental data of known samples, are first transformed int...

We study consistency properties of surrogate loss functions for general multiclass learning problems, defined by a general multiclass loss matrix. We extend the notion of classification calibration, which has been studied for binary and multiclass 0-1 classification problems (and for certain other specific learning problems), to the general multiclass setting, and derive necessary and sufficien...

Dibutyl phthalate (DBP) is a phthalic acid ester and is widely used in polymeric products to make them more flexible. DBP is found in almost every plastic material and is believed to be persistent in the environment. Various analytical methods have been used to measure DBP in different matrices. Considering the ubiquitous nature of DBP, the most important challenge in DBP analyses is the contam...

Dibutyl phthalate (DBP) is a phthalic acid ester and is widely used in polymeric products to make them more flexible. DBP is found in almost every plastic material and is believed to be persistent in the environment. Various analytical methods have been used to measure DBP in different matrices. Considering the ubiquitous nature of DBP, the most important challenge in DBP analyses is the contam...