Here, we report a method to use natural wood lauan as a template to fabricate superhydrophobic biomorphic copper on a carbon substrate (Cu/C). First, a carbon substrate with the microstructure of lauan was obtained by sintering lauan in an oxygen-free environment. A biomorphic Cu/C material was then obtained by immersing this carbon substrate into a Cu(NO3)2 solution and sintering. Finally, the...

In this work, the microwave surface wave plasma (MWSWP) equipment is used to grow the carbon nano-materials at low temperature on different catalysts prepared by the so-called plasma assisted sol-gel synthesis method. Without any additional heating method, the plasma itself can heat up the substrate to about 280oC. By applying the -600V bias voltage, the substrate temperature can reach more tha...

We present a general study on a high performance supercapacitor based on intercalated reduced graphene oxide with carbon black nanoparticles. Graphene oxide sheets were synthesized by oxidation and exfoliation of natural graphite and were reduced using hydroiodic acid in the presence of carbon black nanoparticles. Graphene paper was fabricated by one-step procedure via simultaneous reducing and...

We investigate the interaction of a carbon nanotube with a graphite substrate, using an interlayer potential that explicitly treats the registry dependence of the interaction. The carbon-carbon bond lengths in nanotubes differ slightly from those in flat graphite, so that the naively commensurate angular orientations for the tube with respect to the substrate lattice are destroyed. The interact...

different amounts of nanoclay were incorporated into the acrylic resin matrix at 0, 1, 3, and 5 wt.% loadings. the coatings were applied on low carbon steel plates. optical microscopy, sedimentation test, transmission electron microscopy, and x-ray diffraction were employed to investigate the dispersion of nanoclay in matrix. the corrosion resistance of coatings was evaluated by electrochemical...

A plausible structure of the iron-molybdenum cofactor of nitrogenase [reduced ferredoxin:dinitrogen oxidoreductase (ATP-hydrolyzing), EC 1.18.6.1] is presented based on altered substrate reduction properties of dinitrogenase containing homocitrate analogs within the cofactor. Alterations on each carbon of the four-carbon homocitrate backbone were correlated with altered substrate reduction prop...

The dynamic evolution of nanocatalyst particle shape and carbon composition during the initial stages of single-walled carbon nanotube growth by chemical vapor deposition synthesis is investigated. Classical reactive and ab initio molecular dynamics simulations are used, along with environmental transmission electron microscope video imaging analyses. A clear migration of carbon is detected fro...

production of thermostable alkaline protease in tray bioreactor for solid state fermentation is a unique process which may lead to an economical approach for production of enzyme from agricultural waste or low cost substrate. in solid state fermentation using tray bioreactor, several agricultural residues such as rice bran, sugarcane bagasse, wheat bran, barely bran, corn meal and corn husk wer...

The Diels-Alder reaction is a cornerstone in organic synthesis, forming two carbon-carbon bonds and up to four new stereogenic centers in one step. No naturally occurring enzymes have been shown to catalyze bimolecular Diels-Alder reactions. We describe the de novo computational design and experimental characterization of enzymes catalyzing a bimolecular Diels-Alder reaction with high stereosel...

The unique topology and exceptional properties of carbon nanoscrolls CNSs have inspired unconventional nanodevice concepts, yet the fabrication of CNSs remains rather challenging. Using molecular dynamics simulations, we demonstrate the spontaneous formation of a CNS from graphene on a substrate, initiated by a carbon nanotube CNT . The rolling of graphene into a CNS is modulated by the CNT siz...