Ni-based catalysts with different amounts of Na as promoter from 2 to 6 wt % were prepared by solution combustion method. The catalytic activity was investigated in syngas methanation reaction. Carbon oxides conversion and methane selectivity are greatly influenced by sodium loading. Adding 2 wt% Na remarkably improves catalytic activity and long-term stability, attributed to its smaller mean N...

Nanocrystalline La2Sn2O7 and La2Sn1.8Co0.2O7 with a phase-pure pyrochlore structure were synthesized by a hydrothermal method, and their catalytic activity was investigated for soot combustion. The as-synthesized catalysts presented relatively larger surface area, and pore volume, which was benefit to the gas molecule diffusion in the reaction. A uniform spherical structure with particle size o...

A new functional AlNi-pillared clays (AlNi-PILC) with a large surface area and pore volume was synthesized. The performance of adsorption/desorption-catalytic combustion over CeO2-modified Pd/AlNi-PILC catalysts was also studied. The results showed that the d001-value and specific surface area (SBET) of AlNi-PILC reached 2.11 nm and 374.8 m²/g, respectively. The large SBET and the d001-value im...

A thermoelectric gas sensor (TGS) with a combustion catalyst is a calorimetric sensor that changes the small heat of catalytic combustion into a signal voltage. We analyzed the thermal balance of a TGS to quantitatively estimate the sensor parameters. The voltage signal of a TGS was simulated, and the heat balance was calculated at two sections across the thermoelectric film of a TGS. The therm...

Nano-sized particles of ceria with high surface area were processed by solution combustion synthesis (SCS) and their catalytic activity towards combustion of carbonaceous materials was compared with that obtained by simple thermal decomposition of cerium nitrate, exhibiting the same specific surface area. These two kinds of ceria powders were tested, by DTA and temperature programmed combustion...

During the last decade extensive research has been made at Lund University, Sweden, on a lean premix (prevaporize) combustion concept with burnt gas recirculation and a metallic flame holder. From this concept a new lean premixed natural gas combustion chamber with internal combustion gas recirculation (CGR) has been developed for the V160/SOLO 161 Stirling engines. This combustor has ultra-low...

This work focuses on the development and improvement of numerical tools for the simulation of catalytic monolith reactors. These simulations cover detailed descriptions of reaction mechanisms, transport in gas-phase and washcoats, fluid flow in single channels, and the entire reactor. In DETCHEM, the concept of building a transient model of the monolith reactor by the calculation of steady-stat...

The small radiant heaters that burn hydrocarbon fuels propane, butane, methane/natural gas and liquid hydrocarbon fuels are used widely because of their simple design, their portability, and the ready availability of fuels. The open flame heater presents obvious disadvantages as follows. An upset heater is a grave fire risk where the surroundings are flammable and this restricts usage in, for e...