Steam reforming of ethanol in the membrane reactor using the Pd77Ag23 membrane was evaluated in Ni/CeO2 and Co/CeO2 at atmospheric pressure. At 673 K, the H2 yield in the Pd77Ag23 membrane reactor over Co/CeO2 was found to be higher than that over Ni/CeO2, although the H2 yield over Ni/CeO2 exceeded that over Co/CeO2 at 773 K. This difference was owing to their reaction mechanism. At 773 K, the...

AbstractIn this study, the stress analysis of YBCO/CeO2/YSZ/CeO2/Ni architextured materials under cryogenic conditions was carried out for coated conductor applications. YBCO/CeO2/YSZ/CeO2 multilayer films were fabricated on Ni tape substrate using reel-to-reel sol-gel and Pulse Laser Deposition (PLD) systems. The microstructural evolution of high temperature superconducting YBCO film and buffe...

Ni–CeO2–ZrO2 Catalysts for Water Gas Shift Reaction: Effect of CeO2

OBJECTIVE Cerium oxide (CeO2) nanoparticles have been shown to protect cells in culture from lethal stress, but no protection in vivo has been reported. Cardiac-specific expression of monocyte chemoattractant protein (MCP)-1 in mice causes ischemic cardiomyopathy associated with activation of endoplasmic reticulum (ER) stress. The aim of this study was to assess the effects of CeO2 nanoparticle...

This paper reports the synthesis of CeO2/ZrO2 nanocomposite by wet chemical method using cationic surfactant (CTAB). The properties of the obtained nanocomposites were analysed by X-ray diffraction (XRD), Fourier transform infrared (FTIR), scanning electron microscoy (SEM), transmission electron microscopy (TEM), UV-Diffuse Reflectance Spectroscopy (UV-DRS) and photoluminescence (PL) spectrosco...

A low-concentration cobalt (∼6 at%) and manganese (∼3 at%) bimetallic oxide catalyst supported on ceria nanorods (CoMnOx/CeO2), as well as its related single metal oxide counterparts (CoOx/CeO2 and MnOx/CeO2) was synthesized via a deposition-precipitation approach. The fresh samples after air-calcination at 400 °C were tested under the reaction conditions of CO oxidation, and showed the followi...

CeO2 nanoparticles (NPs) have been well demonstrated as an antioxidant in protecting against oxidative stress-induced cellular damages and a potential therapeutic agent for various diseases thanks to their redox enzyme-mimicking activities. The Ce3+/Ce4+ ratio and oxygen vacancies on the surface have been considered as the major originations responsible for the redox enzyme-mimicking activities...

For the first time we synthesized mesoporous CeO2 nanosheets with single-crystal-like, ultrathin and uniform-sized structures through the thermal decomposition of specially prepared intermediates of Ce(OH)CO3 nanosheets. The resulting single-crystal-like CeO2 porous nanosheets are only 2.4 nm thick, as measured by AFM. BET analysis indicated that the pores of the nanosheets were centered at 3.7...